ChemInform Abstract: A NEW TYPE OF PHOSPHORUS-CARBON AND CARBON-CARBON BOND CLEAVAGE REACTIONS IN α-(TRIMETHYLSILYLOXY)-β-OXO PHOSPHONATES AND α-ETHOXY-β-OXO PHOSPHONATES. THE SYNTHESIS OF UNSYMMETRICAL α-HYDROXY KETONES UTILIZING 1:1 CARBONYL ADDUCTS OF

1982 ◽  
Vol 13 (17) ◽  
Author(s):  
M. SEKINE ◽  
H. NAKAJIMA ◽  
T. HATA
Keyword(s):  
Bond Cleavage ◽  
Carbon Bond ◽  
Carbon Carbon Bond ◽  
Hydroxy Ketones ◽  
New Type ◽  
Cleavage Reactions

Cleavage of carbon–carbon bonds by radical reactions

2019 ◽  
Vol 48 (9) ◽  
pp. 2615-2656 ◽  
Author(s):  
Paramasivam Sivaguru ◽  
Zikun Wang ◽  
Giuseppe Zanoni ◽  
Xihe Bi
Keyword(s):  
Bond Cleavage ◽  
Radical Reactions ◽  
Carbon Bond ◽  
Carbon Carbon Bond ◽  
Carbon Carbon Bonds ◽  
Carbon Bonds ◽  
Cleavage Reactions

This review provides insights into the in situ generated radicals triggered carbon–carbon bond cleavage reactions.

Anion Effects in Oxidative Aliphatic Carbon–Carbon Bond Cleavage Reactions of Cu(II) Chlorodiketonate Complexes

2016 ◽  
Vol 55 (14) ◽  
pp. 6916-6928 ◽  
Author(s):  
Sushma L. Saraf ◽  
Anna Miłaczewska ◽  
Tomasz Borowski ◽  
Christopher D. James ◽  
David L. Tierney ◽  
...  
Keyword(s):  
Bond Cleavage ◽  
Carbon Bond ◽  
Carbon Carbon Bond ◽  
Aliphatic Carbon ◽  
Cleavage Reactions

NOVEL CARBON–CARBON BOND CLEAVAGE REACTIONS OF α-AZOHYDROPEROXIDES

1982 ◽  
Vol 11 (10) ◽  
pp. 1607-1610 ◽  
Author(s):  
Masanori Utaka ◽  
Yuji Fujita ◽  
Akira Takeda
Keyword(s):  
Bond Cleavage ◽  
Carbon Bond ◽  
Carbon Carbon Bond ◽  
Cleavage Reactions

Organocatalytic Difluorobenzylation of 1,2-Diketones via Mild Cleavage of Carbon−Carbon Bonds

2022 ◽  
Author(s):  
Yong Zhang ◽  
Guo-Wei Lai ◽  
Long-Jun Nie ◽  
Qifang He ◽  
Mei-Juan Lin ◽  
...  
Keyword(s):  
Bond Cleavage ◽  
Carbon Bond ◽  
Carbon Carbon Bond ◽  
Carbon Carbon Bonds ◽  
Carbon Bonds ◽  
New Type

α-aryl-α,α-Difluoroacetophenones (DFAPs) are developed as a new type of difluorobenzylation reagents that can be facilely prepared from readily available and cheap starting materials. In-situ carbon-carbon bond cleavage of electron-deficient DFAPs...

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