Cleavage of carbon–carbon bonds by radical reactions

2019 ◽  
Vol 48 (9) ◽  
pp. 2615-2656 ◽  
Author(s):  
Paramasivam Sivaguru ◽  
Zikun Wang ◽  
Giuseppe Zanoni ◽  
Xihe Bi
Keyword(s):  
Bond Cleavage ◽  
Radical Reactions ◽  
Carbon Bond ◽  
Carbon Carbon Bond ◽  
Carbon Carbon Bonds ◽  
Carbon Bonds ◽  
Cleavage Reactions

This review provides insights into the in situ generated radicals triggered carbon–carbon bond cleavage reactions.

Organocatalytic Difluorobenzylation of 1,2-Diketones via Mild Cleavage of Carbon−Carbon Bonds

2022 ◽  
Author(s):  
Yong Zhang ◽  
Guo-Wei Lai ◽  
Long-Jun Nie ◽  
Qifang He ◽  
Mei-Juan Lin ◽  
...  
Keyword(s):  
Bond Cleavage ◽  
Carbon Bond ◽  
Carbon Carbon Bond ◽  
Carbon Carbon Bonds ◽  
Carbon Bonds ◽  
New Type

α-aryl-α,α-Difluoroacetophenones (DFAPs) are developed as a new type of difluorobenzylation reagents that can be facilely prepared from readily available and cheap starting materials. In-situ carbon-carbon bond cleavage of electron-deficient DFAPs...

Iridium-catalysed hydrosilylation of cyclopropanes via regioselective carbon–carbon bond cleavage

2017 ◽  
Vol 53 (66) ◽  
pp. 9281-9284 ◽  
Author(s):  
Masahito Murai ◽  
Atsushi Nishiyama ◽  
Naoki Nishinaka ◽  
Haruka Morita ◽  
Kazuhiko Takai
Keyword(s):  
Bond Cleavage ◽  
Carbon Bond ◽  
Carbon Carbon Bond ◽  
Carbon Carbon Bonds ◽  
Carbon Bonds

Catalytic and regioselective hydrosilylation of electronically unactivated cyclopropanes via the selective cleavage of proximal carbon–carbon bonds was developed.

scholarly journals Metal-free visible light photoredox enables generation of carbyne equivalents via phosphonium ylide C–H activation

2019 ◽  
Vol 10 (6) ◽  
pp. 1687-1691 ◽  
Author(s):  
Mrinmoy Das ◽  
Minh Duy Vu ◽  
Qi Zhang ◽  
Xue-Wei Liu
Keyword(s):  
Visible Light ◽  
Bond Formation ◽  
Formation Processes ◽  
New Approach ◽  
Carbon Bond ◽  
Metal Free ◽  
Carbon Carbon Bond ◽  
Carbon Carbon Bonds ◽  
Carbon Bonds ◽  
New Strategy

Phosphonium ylides have shown their synthetic usefulness in important carbon–carbon bond formation processes. Our new strategy employs phosphonium ylides as novel carbyne equivalents and features a new approach for constructing carbon–carbon bonds from alkenes.

Carbon-carbon bond cleavage reactions in the decomposition of metallacycles

1978 ◽  
Vol 100 (23) ◽  
pp. 7418-7420 ◽  
Author(s):  
Robert H. Grubbs ◽  
Akira Miyashita
Keyword(s):  
Bond Cleavage ◽  
Carbon Bond ◽  
Carbon Carbon Bond ◽  
Cleavage Reactions

Anion Effects in Oxidative Aliphatic Carbon–Carbon Bond Cleavage Reactions of Cu(II) Chlorodiketonate Complexes

2016 ◽  
Vol 55 (14) ◽  
pp. 6916-6928 ◽  
Author(s):  
Sushma L. Saraf ◽  
Anna Miłaczewska ◽  
Tomasz Borowski ◽  
Christopher D. James ◽  
David L. Tierney ◽  
...  
Keyword(s):  
Bond Cleavage ◽  
Carbon Bond ◽  
Carbon Carbon Bond ◽  
Aliphatic Carbon ◽  
Cleavage Reactions

NOVEL CARBON–CARBON BOND CLEAVAGE REACTIONS OF α-AZOHYDROPEROXIDES

1982 ◽  
Vol 11 (10) ◽  
pp. 1607-1610 ◽  
Author(s):  
Masanori Utaka ◽  
Yuji Fujita ◽  
Akira Takeda
Keyword(s):  
Bond Cleavage ◽  
Carbon Bond ◽  
Carbon Carbon Bond ◽  
Cleavage Reactions
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