ChemInform Abstract: AN ANOMALOUS REACTION OF 10-CHLORO-5H-BENZOXAZOLO(3,2-A)QUINOLIN-5-ONE WITH SODIUM DIETHYL MALONATE TO FORM 9-CHLORO-8-ETHOXY-12-HYDROXY-5H-DIBENZO(C,F)QUINOLIZIN-5-ONE

1982 ◽  
Vol 13 (39) ◽  
Author(s):  
D. H. KIM
Keyword(s):  
Diethyl Malonate ◽  
Anomalous Reaction ◽  
Sodium Diethyl Malonate

scholarly journals On the hydrolysis of diethyl 2-(perfluorophenyl)malonate

2020 ◽  
Vol 16 ◽  
pp. 1863-1868
Author(s):  
Ilya V Taydakov ◽  
Mikhail A Kiskin
Keyword(s):  
Acetic Acid ◽  
Malonic Acid ◽  
Diethyl Malonate ◽  
Toxic Substances ◽  
New Approach ◽  
Preparative Yield ◽  
Benzyl Halides ◽  
Acidic Conditions ◽  
Hydrolysis Of ◽  
Sodium Diethyl Malonate

Diethyl 2-(perfluorophenyl)malonate was synthesized in 47% isolated yield by the reaction of sodium diethyl malonate and hexafluorobenzene. The resulting compound was considered as a starting material for synthesizing 2-(perfluorophenyl)malonic acid by hydrolysis. It was found that the desired 2-(perfluorophenyl)malonic acid could not be obtained from this ester by hydrolysis, neither under basic nor under acidic conditions. Nevertheless, hydrolysis of the ester with a mixture of HBr and AcOH gave 2-(perfluorophenyl)acetic acid in a good preparative yield of 63%. A significant advantage of this new approach to 2-(perfluorophenyl)acetic acid is that handling toxic substances such as cyanides and perfluorinated benzyl halides is avoided.

ChemInform Abstract: Reactions of Sodium Diethyl Malonate with Functionalized 2,3-Dichlorocyclopentenones. Preparation of Water-Soluble Derivatives.

ChemInform ◽  
2010 ◽  
Vol 30 (50) ◽  
pp. no-no
Author(s):  
N. A. Ivanova ◽  
A. M. Shainurova ◽  
R. R. Akhmetvaleev ◽  
T. A. Belogaeva ◽  
M. S. Miftakhov
Keyword(s):  
Diethyl Malonate ◽  
Water Soluble ◽  
Sodium Diethyl Malonate

Preparation and absolute configuration at C(20) of 21-nor-5α-cholan-24→20-olide derivatives

1981 ◽  
Vol 46 (1) ◽  
pp. 107-117 ◽  
Author(s):  
Vladimír Pouzar ◽  
Miroslav Havel
Keyword(s):  
Acetic Acid ◽  
Absolute Configuration ◽  
Nmr Spectra ◽  
Lithium Salt ◽  
Diethyl Malonate ◽  
Methyl Propionate ◽  
H Nmr ◽  
Sodium Diethyl Malonate

The lactones X and XI were obtained on reaction of the aldehyde III with lithium salt of methyl propionate followed by hydrogenation of the intermediary esters IV and V. Treatment of the epoxides XXI and XXII with dilithium salt of acetic acid yielded the lactones X and XI. These lactones were also obtained by reaction of the epoxides XXI and XXII with sodium diethyl malonate through intermediates XXIII and XXV. The preparation of α-methylene lactones XXVII and XXVIII is also described. The 20R configuration was established for the lactones X, XXIII and XXVII while the lactones XI, XXV and XXVIII were assigned the 20S configuration both on the basis of 1H-NMR spectra and chemical correlations.

Rearrangement of a Vinylallylammonium Salt Effected by Sodium Diethyl Malonate

2004 ◽  
Vol 74 (1) ◽  
pp. 144-145 ◽  
Author(s):  
S. T. Kocharyan ◽  
V. S. Ovsepyan ◽  
A. V. Babakhanyan ◽  
V. E. Karapetyan ◽  
G. A. Panosyan
Keyword(s):  
Diethyl Malonate ◽  
Sodium Diethyl Malonate

ChemInform Abstract: ANOMALOUS REACTION OF 3-METHYL-2-CYCLOPENTEN-1-ONE WITH N-BUTYL NITRITE

1978 ◽  
Vol 9 (13) ◽  
Author(s):  
V. L. NOVIKOV ◽  
O. P. SHESTAK ◽  
G. B. ELYAKOV
Keyword(s):  
Anomalous Reaction

scholarly journals Anomalous reaction mean free paths of nuclear projectile fragments from heavy ion collisions at2AGeV

1983 ◽  
Vol 27 (4) ◽  
pp. 1489-1520 ◽  
Author(s):  
E. M. Friedlander ◽  
R. W. Gimpel ◽  
H. H. Heckman ◽  
Y. J. Karant ◽  
B. Judek ◽  
...  
Keyword(s):  
Heavy Ion Collisions ◽  
Heavy Ion ◽  
Ion Collisions ◽  
Anomalous Reaction

Reaction of α-ethoxyarolein with diethyl malonate

1998 ◽  
Vol 47 (12) ◽  
pp. 2426-2428 ◽  
Author(s):  
N. A. Keiko ◽  
Yu. A. Chuvashev ◽  
T. A. Kuznetsova ◽  
L. V. Sherstyannikova ◽  
M. G. Voronkov
Keyword(s):  
Diethyl Malonate
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