ChemInform Abstract: FLUORIDE ION CATALYZED ALDOL REACTION BETWEEN ENOL SILYL ETHERS AND CARBONYL COMPOUNDS

1983 ◽  
Vol 14 (39) ◽  
Author(s):  
E. NAKAMURA ◽  
M. SHIMIZU ◽  
I. KUWAJIMA ◽  
J. SAKATA ◽  
K. YOKOYAMA ◽  
...  
Keyword(s):  
Carbonyl Compounds ◽  
Aldol Reaction ◽  
Fluoride Ion ◽  
Silyl Ethers ◽  
Enol Silyl Ethers

Fluoride ion catalyzed aldol reaction between enol silyl ethers and carbonyl compounds

1983 ◽  
Vol 48 (7) ◽  
pp. 932-945 ◽  
Author(s):  
Eiichi Nakamura ◽  
Makoto Shimizu ◽  
Isao Kuwajima ◽  
J. Sakata ◽  
K. Yokoyama ◽  
...  
Keyword(s):  
Carbonyl Compounds ◽  
Aldol Reaction ◽  
Fluoride Ion ◽  
Silyl Ethers ◽  
Enol Silyl Ethers

ChemInform Abstract: FLUORIDE ION CATALYZED ALDOL REACTION BETWEEN ENOL SILYL ETHERS AND CARBONYL COMPOUNDS

1977 ◽  
Vol 8 (19) ◽  
pp. no-no
Author(s):  
R. NOYORI ◽  
K. YOKOYAMA ◽  
J. SAKATA ◽  
I. KUWAJIMA ◽  
E. NAKAMURA ◽  
...  
Keyword(s):  
Carbonyl Compounds ◽  
Aldol Reaction ◽  
Fluoride Ion ◽  
Silyl Ethers ◽  
Enol Silyl Ethers

Fluoride ion catalyzed aldol reaction between enol silyl ethers and carbonyl compounds

1977 ◽  
Vol 99 (4) ◽  
pp. 1265-1267 ◽  
Author(s):  
R. Noyori ◽  
K. Yokoyama ◽  
J. Sakata ◽  
Isao Kuwajima ◽  
Eiichi Nakamura ◽  
...  
Keyword(s):  
Carbonyl Compounds ◽  
Aldol Reaction ◽  
Fluoride Ion ◽  
Silyl Ethers ◽  
Enol Silyl Ethers

[3+2] Cycloaddition of 2-Alkoxycyclopropyl Carbonyl Compounds with Enol Silyl Ethers for Functionalized Cyclopentane Formation

Synlett ◽  
1991 ◽  
Vol 1991 (11) ◽  
pp. 771-773 ◽  
Author(s):  
Makoto Komatsu ◽  
Ichiro Suehiro ◽  
Yoshiaki Horiguchi ◽  
Isao Kuwajima
Keyword(s):  
Carbonyl Compounds ◽  
Silyl Ethers ◽  
Enol Silyl Ethers

An efficient catalyst-free Mukaiyama-aldol reaction of fluorinated enol silyl ethers with tryptanthrin

2015 ◽  
Vol 13 (33) ◽  
pp. 8906-8911 ◽  
Author(s):  
Fu-Min Liao ◽  
Yun-Lin Liu ◽  
Jin-Sheng Yu ◽  
Feng Zhou ◽  
Jian Zhou
Keyword(s):  
Total Synthesis ◽  
Natural Product ◽  
Aldol Reaction ◽  
Efficient Catalyst ◽  
Silyl Ethers ◽  
Mukaiyama Aldol Reaction ◽  
Catalyst Free ◽  
Mukaiyama Aldol ◽  
Enol Silyl Ethers ◽  
Fluoroalkyl Group

We report an efficient Mukaiyama-aldol reaction of tryptanthrin with fluorinated enol silyl ethers, which is carried out in methanol without the use of any catalyst. This represents the first modification of tryptanthrin by a fluoroalkyl group, which is applied to the total synthesis of the difluoro analogues of the natural product Phaitanthrin B.

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