ChemInform Abstract: PHENYLATION OF ACYCLIC ALLYLIC ALCOHOLS. II. REGIOSELECTIVITY OF HYDROGEN TRANSFER

Chemischer Informationsdienst ◽

10.1002/chin.198434162 ◽

1984 ◽

Vol 15 (34) ◽

Author(s):

W. SMADJA ◽

G. VILLE ◽

G. CAHIEZ

Keyword(s):

Hydrogen Transfer ◽

Allylic Alcohols

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Chemoselective Hydrogen Transfer Reduction of Unsaturated Ketones to Allylic Alcohols with Solid Zr and Hf Catalysts.

10.1002/chin.200315063 ◽

2003 ◽

Vol 34 (15) ◽

Author(s):

Mario De bruyn ◽

Dirk E. De Vos ◽

Pierre A. Jacobs

Keyword(s):

Hydrogen Transfer ◽

Allylic Alcohols ◽

Unsaturated Ketones

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Disproportionation of acyclic ketones to carboxylate ions and ethers: a poisoning reaction on the way to the chemoselective reduction of α,β-unsaturated ketones to allylic alcohols via hydrogen-transfer catalysed by a nonclassical ruthenium(II) trihydride

Journal of the Chemical Society Chemical Communications ◽

10.1039/c39910001336 ◽

1991 ◽

pp. 1336-1337 ◽

Author(s):

Claudio Bianchini ◽

Erica Farnetti ◽

Piero Frediani ◽

Mauro Graziani ◽

Maurizio Peruzzini ◽

...

Keyword(s):

Hydrogen Transfer ◽

Allylic Alcohols ◽

Unsaturated Ketones ◽

Acyclic Ketones ◽

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Catalytic hydrogen-transfer reactions of benzylic and allylic alcohols with palladium compounds in the presence of vinyl acetate or under an ethylene atmosphere

Journal of the Chemical Society Perkin Transactions 1 ◽

10.1039/b001385o ◽

2000 ◽

pp. 1501-1503 ◽

Author(s):

Masahiko Hayashi ◽

Kanako Yamada ◽

Shu-zo Nakayama

Keyword(s):

Vinyl Acetate ◽

Hydrogen Transfer ◽

Transfer Reactions ◽

Allylic Alcohols ◽

Palladium Compounds ◽

Catalytic Hydrogen ◽

Catalytic Hydrogen Transfer ◽

Hydrogen Transfer Reactions

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Chemoselective Hydrogen Transfer Reduction of Unsaturated Ketones to Allylic Alcohols with Solid Zr and Hf Catalysts

Advanced Synthesis & Catalysis ◽

10.1002/1615-4169(200212)344:10<1120::aid-adsc1120>3.0.co;2-4 ◽

2002 ◽

Vol 344 (10) ◽

pp. 1120-1125 ◽

Author(s):

Mario De bruyn ◽

Dirk E. De Vos ◽

Pierre A. Jacobs

Keyword(s):

Hydrogen Transfer ◽

Allylic Alcohols ◽

Unsaturated Ketones

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Regioselective Reduction of α,β-Unsaturated Carbonyl Compounds to Allylic Alcohols by Vapor Phase Hydrogen Transfer Reaction over MgO-B2O3Catalyst

Chemistry Letters ◽

10.1246/cl.1992.1345 ◽

1992 ◽

Vol 21 (7) ◽

pp. 1345-1348 ◽

Author(s):

Michio Ueshima ◽

Yuuji Shimasaki

Keyword(s):

Vapor Phase ◽

Carbonyl Compounds ◽

Hydrogen Transfer ◽

Transfer Reaction ◽

Allylic Alcohols ◽

Hydrogen Transfer Reaction

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Hydrogen transfer reaction of allylic alcohols catalyzed by a molybdenum complex

Journal of Organometallic Chemistry ◽

10.1016/s0022-328x(00)98777-1 ◽

1983 ◽

Vol 251 (3) ◽

pp. 321-325 ◽

Author(s):

Yingrui Lin ◽

Xiyan Lu

Keyword(s):

Hydrogen Transfer ◽

Transfer Reaction ◽

Allylic Alcohols ◽

Molybdenum Complex ◽

Hydrogen Transfer Reaction

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ChemInform Abstract: Catalytic Hydrogen-Transfer Reactions of Benzylic and Allylic Alcohols with Palladium Compounds in the Presence of Vinyl Acetate or under an Ethylene Atmosphere.

10.1002/chin.200039079 ◽

2000 ◽

Vol 31 (39) ◽

pp. no-no

Author(s):

Masahiko Hayashi ◽

Kanako Yamada ◽

Shu-zo Nakayama

Keyword(s):

Vinyl Acetate ◽

Hydrogen Transfer ◽

Transfer Reactions ◽

Allylic Alcohols ◽

Palladium Compounds ◽

Catalytic Hydrogen ◽

Catalytic Hydrogen Transfer ◽

Hydrogen Transfer Reactions

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ChemInform Abstract: Regioselective Reduction of α,β-Unsaturated Carbonyl Compounds to Allylic Alcohols by Vapor Phase Hydrogen Transfer Reaction over MgO-B2O3 Catalyst.

10.1002/chin.199314104 ◽

2010 ◽

Vol 24 (14) ◽

pp. no-no

Author(s):

M. UESHIMA ◽

Y. SHIMASAKI

Keyword(s):

Vapor Phase ◽

Carbonyl Compounds ◽

Hydrogen Transfer ◽

Transfer Reaction ◽

Allylic Alcohols ◽

Hydrogen Transfer Reaction

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Manganese Catalyzed Anti-Markovnikov Hydroamination of Allyl Alcohols via Hydrogen Borrowing Catalysis

10.26434/chemrxiv.14216921 ◽

2021 ◽

Author(s):

Kuhali Das ◽

Koushik Sarkar ◽

Biplab Maji

Keyword(s):

Amino Alcohol ◽

Hydrogen Transfer ◽

Phosphine Ligand ◽

Transfer Mechanism ◽

Allylic Alcohols ◽

Drug Molecules ◽

Ligand Free ◽

Free Hydrogen ◽

Synthetic Intermediates ◽

A phosphine ligand free manganese(I)-complex catalyzed the selective anti-Markovnikov hydroamination of allylic alcohols <i>via</i> waste-free hydrogen transfer mechanism. The γ-amino alcohol products are versatile synthetic intermediates for the synthesis of several drug molecules.

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Highly Efficient Kinetic Resolution of Aryl-Alkenyl Alcohols by Ru-Catalyzed Hydrogen Transfer

Molecules ◽

10.3390/molecules26247475 ◽

2021 ◽

Vol 26 (24) ◽

pp. 7475

Author(s):

Yipeng You ◽

Ming Yu Jin ◽

Guanyu Tao ◽

Xiangyou Xing

Keyword(s):

Organic Synthesis ◽

Hydrogen Transfer ◽

Kinetic Resolution ◽

Asymmetric Reduction ◽

Building Blocks ◽

Enantioselective Synthesis ◽

Allylic Alcohols ◽

Secondary Alcohols ◽

Highly Efficient ◽

Reduction Of Ketones

No matter through asymmetric reduction of ketones or kinetic resolution of secondary alcohols, enantioselective synthesis of the corresponding secondary alcohols is challenging when the two groups attached to the prochiral or chiral centers are spatially or electronically similar. For examples, dialkyl (sp3 vs. sp3), diaryl (sp2 vs. sp2), and aryl-alkenyl (sp2 vs. sp2) alcohols are difficult to produce with high enantioselectivities. By exploiting our recently developed Ru-catalysts of minimal stereogenicity, we reported herein a highly efficient kinetic resolution of aryl-alkenyl alcohols through hydrogen transfer. This method enabled such versatile chiral building blocks for organic synthesis as allylic alcohols, to be readily accessed with excellent enantiomeric excesses at practically useful conversions.

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