ChemInform Abstract: Synthesis of New Ferrocenyl Amine Sulfide and Selenide Complexes of Group 10 Metals and Their Catalytic Activities Toward Selective Hydrogenation, Isomerization, and Asymmetric Grignard Cross-Coupling Reactions.

ChemInform ◽  
1990 ◽  
Vol 21 (40) ◽  
Author(s):  
A. A. NAIINI ◽  
C.-K. LAI ◽  
D. L. WARD ◽  
C. H. JUN. BRUBAKER
Keyword(s):  
Selective Hydrogenation ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Catalytic Activities ◽  
Cross Coupling Reactions ◽  
Group 10 ◽  
Group 10 Metals

Agglomeration of Pd0 nanoparticles causing different catalytic activities of Suzuki carbonylative cross-coupling reactions catalyzed by PdII and Pd0 immobilized on dopamine-functionalized magnetite nanoparticles

2015 ◽  
Vol 39 (4) ◽  
pp. 2988-2996 ◽  
Author(s):  
Yu Long ◽  
Kun Liang ◽  
Jianrui Niu ◽  
Xin Tong ◽  
Bing Yuan ◽  
...  
Keyword(s):  
Magnetite Nanoparticles ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Catalytic Activities ◽  
Cross Coupling Reactions

Agglomeration of Pd0 nanoparticles caused different catalytic activities of Suzuki carbonylative cross-coupling reactions catalyzed by Fe3O4/DA–PdII and Fe3O4/DA–Pd0 catalysts.

scholarly journals POxAP Precatalysts and the Negishi Cross-Coupling Reaction

Synthesis ◽  
2019 ◽  
Vol 52 (01) ◽  
pp. 51-59
Author(s):  
Shuang-Qi Tang ◽  
Martine Schmitt ◽  
Frédéric Bihel
Keyword(s):  
Functional Groups ◽  
Oxidative Addition ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Catalytic Activities ◽  
Cross Coupling Reactions ◽  
Cross Coupling Reaction ◽  
Wide Range ◽  
Organozinc Reagents

Recently developed for the Fukuyama reaction, post-oxidative addition precatalysts (POxAPs) are also very efficient in catalyzing Negishi cross-coupling reactions between organohalides and organozinc reagents. Using very low catalyst loadings, POxAPs show similar catalytic activities to those of classical precatalysts such as XPhos Pd G4 or PEPPSI-IPr, with turnover numbers of up to 93,000. POxAPs are easily prepared, are stable to air and moisture, tolerate a wide range of functional groups in the Negishi cross-coupling reaction and contribute advantageously to the arsenal of organic chemists in terms of Pd precatalysts.

Synthesis of pyrethroids and jasmonoids by palladium-catalyzed cross coupling reactions

Synthesis ◽  
2022 ◽  
Author(s):  
Florencia Parpal ◽  
Ana Paula Paullier ◽  
Enrique Pandolfi ◽  
Viviana Lucía Heguaburu
Keyword(s):  
Selective Hydrogenation ◽  
Common Core ◽  
Cross Coupling ◽  
Side Chains ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
Defensive Role ◽  
Palladium Catalyzed

The synthesis of jasmone and related jasmonoids and pyrethroids is described. These types of compounds play a defensive role in plants, and share a cyclopentenone common core, with variations in its side chains. Jasmone, cinerone, allylrethrone and derivatives are synthesized through π-allyl palladium cross coupling of stannane derivatives. By selective hydrogenation dihydrojasmone and dihydrocinerone are also synthesized.

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