ChemInform Abstract: Studies on N-Metalloimines: Synthesis of N-Unsubstituted Aziridines ( VI), (VII) from N-Trimethylsilylimines (III), and Lithium Enolates (V) of α-Halo Esters.

ChemInform ◽  
2010 ◽  
Vol 22 (49) ◽  
pp. no-no
Author(s):  
G. CAINELLI ◽  
M. PANUNZIO ◽  
D. GIACOMINI
Keyword(s):  
Lithium Enolates

Umpolung of Fluoroform by CF Bond Activation: Direct Difluoromethylation of Lithium Enolates

2012 ◽  
Vol 124 (38) ◽  
pp. 9673-9676 ◽  
Author(s):  
Toshiaki Iida ◽  
Ryota Hashimoto ◽  
Kohsuke Aikawa ◽  
Shigekazu Ito ◽  
Koichi Mikami
Keyword(s):  
Bond Activation ◽  
Lithium Enolates

scholarly journals The facile dearomatization of nitroaromatic compounds using lithium enolates of unsaturated ketones in conjugate additions and (4+2) formal cycloadditions

2019 ◽  
Vol 55 (52) ◽  
pp. 7494-7497 ◽  
Author(s):  
Karine Pasturaud ◽  
Batoul Rkein ◽  
Morgane Sanselme ◽  
Muriel Sebban ◽  
Sami Lakhdar ◽  
...  
Keyword(s):  
Nitroaromatic Compounds ◽  
The Novel ◽  
Conjugate Additions ◽  
Unsaturated Ketones ◽  
Lithium Enolates

The novel nucleophilic activation of enolizable unsaturated ketones allows their addition to nitroaromatics and furnishes the corresponding formal dearomatized (4+2) cycloadducts.

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