ChemInform Abstract: Stereoselective Synthesis of cis-Decalins via Diels-Alder and Double Michael Addition of Substituted Nazarov Reagents.

ChemInform ◽  
2010 ◽  
Vol 24 (5) ◽  
pp. no-no
Author(s):  
J.-F. LAVALLEE ◽  
C. SPINO ◽  
R. RUEL ◽  
K. T. HOGAN ◽  
P. DESLONGCHAMPS
1992 ◽  
Vol 70 (5) ◽  
pp. 1406-1426 ◽  
Author(s):  
Jean-François Lavallée ◽  
Claude Spino ◽  
Réjean Ruel ◽  
Keith T. Hogan ◽  
Pierre Deslongchamps

The base-catalyzed cycloaddition and double Michael cyclization of substituted Nazarov reagents and of 1-phenylsulfinyl analogs, with 2-carbomethoxy-2-cyclohexen-1-one 1 yielding cis-decalins is reported. The reaction is highly stereoselective affording cis,cis- or cis, trans-decalins. Mechanistic aspects are briefly discussed.


2011 ◽  
Vol 2011 (32) ◽  
pp. 6558-6566 ◽  
Author(s):  
Bettina M. Ruff ◽  
Sabilla Zhong ◽  
Martin Nieger ◽  
Marcel Sickert ◽  
Christoph Schneider ◽  
...  

Author(s):  
Mohammad Bagher Teimouri ◽  
Zahra Mokhtare ◽  
Hamid Reza Khavasi

Three new chemical bonds and three stereogenic centres and one heterocyclic ring were assembled stereoselectively in a convenient high atom-economy one-pot operation.


2010 ◽  
Vol 51 (17) ◽  
pp. 2305-2308 ◽  
Author(s):  
J.S. Yadav ◽  
B.V. Subba Reddy ◽  
A.V. Hara Gopal ◽  
R. Nageshwar Rao ◽  
R. Somaiah ◽  
...  

ChemInform ◽  
2015 ◽  
Vol 46 (31) ◽  
pp. no-no
Author(s):  
Elzbieta Wojaczynska ◽  
Jacek Wojaczynski ◽  
Karolina Kleniewska ◽  
Mateusz Dorsz ◽  
Tomasz K. Olszewski

2011 ◽  
Vol 2011 (9) ◽  
pp. 1714-1720 ◽  
Author(s):  
H. Bauke Albada ◽  
Fiora Rosati ◽  
David Coquière ◽  
Gerard Roelfes ◽  
Rob M. J. Liskamp

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