ChemInform Abstract: Organo-Phosphorus Chemistry. Part 23. The Reaction of α,β- Unsaturated Nitriles with Alkyl Phosphites and Phosphorus Ylides.

ChemInform ◽  
2010 ◽  
Vol 24 (42) ◽  
pp. no-no
Author(s):  
M. R. MAHRAN ◽  
W. M. ABDOU ◽  
N. M. A. EL-RAHMAN ◽  
M. D. KHIDRE
Keyword(s):  
Phosphorus Ylides ◽  
Alkyl Phosphites ◽  
Phosphorus Chemistry

Organophosphorus chemistry 23 [1], the reaction of ?,?-unsaturated nitriles with alkyl phosphites and phosphorus ylides

1992 ◽  
Vol 3 (2) ◽  
pp. 93-99 ◽  
Author(s):  
Mohamed R. Mahran ◽  
Wafaa M. Abdou ◽  
Naglaa M. AbdEl-Rahman ◽  
Maha D. Khidre
Keyword(s):  
Phosphorus Ylides ◽  
Organophosphorus Chemistry ◽  
Alkyl Phosphites

A Simplified Protocol for the Stereospecific Nickel-Catalyzed C–S Vinylation Using NiX2 Salts and Alkyl Phosphites

Synthesis ◽  
2019 ◽  
Vol 52 (02) ◽  
pp. 311-319
Author(s):  
Austin D. Marchese ◽  
Bijan Mirabi ◽  
Egor M. Larin ◽  
Mark Lautens
Keyword(s):  
Cross Coupling ◽  
Robust Method ◽  
Alkyl Phosphites

A Ni-catalyzed C–S cross-coupling using only NiI2 (0.5–2.5 mol%) and P(OiPr)3 (2.0–10.0 mol%) is reported. Using an air-stable Ni(II) precatalyst, and a cheap and commercially available ligand, a scalable and robust method was developed to cross-couple various thiophenols and styryl bromides, including some sterically encumbered thiols, an α-bromocinnamaldehyde as well as a thiolation-cyclization.

Chemistry of Phosphorus Ylides. Part 27. Metal Complexes of 4-hydroxyquinaldine, its Mannich Base and Phosphonium Ylide

2009 ◽  
Vol 2009 (5) ◽  
pp. 277-282 ◽  
Author(s):  
Fouad Soliman ◽  
Ibrahim Abd-Ellah ◽  
Soher Maigali ◽  
Gamal Abd-El-Naim
Keyword(s):  
Nitrogen Atom ◽  
Metal Complexes ◽  
Mannich Base ◽  
Phosphorus Ylides ◽  
Physicochemical Data

The reaction of Hg2+,Cd2+,Co2+, and Ni2+ ions with 1 mol of the ligands 2-methylquinoline-4-ol,3[(diethylamino)methyl]-2-methylquinoline-4-ol, and methyl-3-(4-hyrdoxy-2-methylquinoline-3-yl)-2-(triphenylphosphoranylidene)propanoate, has been investigated to give the corresponding 1:1 metal:ligand complexes. Reaction of 2 mol of the ligand gave the corresponding 1:2 metal:ligand complexes. The coordination takes place only through the quinoline nitrogen atom. The spectroscopic and the physicochemical data of the new metal complexes are discussed.

THE BEHAVIOR OF AZIDO-p-QUINONEIMINES TOWARDS ALKYL PHOSPHITES AND TRIPHENYLPHOSPHINE

2002 ◽  
Vol 32 (4) ◽  
pp. 591-603 ◽  
Author(s):  
N. Khir-el-Din ◽  
A. A. Nada ◽  
M. Ramla ◽  
M. F. Zayed
Keyword(s):  
Alkyl Phosphites

ChemInform Abstract: Mechanistic Investigations on the Reaction Between 1,2-Dioxines and Bulky Stabilized Phosphorus Ylides: An Efficient Route to Closely Related Cyclopropane Stereoisomers.

ChemInform ◽  
2010 ◽  
Vol 33 (19) ◽  
pp. no-no
Author(s):  
Thomas D. Avery ◽  
Gary Fallon ◽  
Ben W. Greatrex ◽  
Simon M. Pyke ◽  
Dennis K. Taylor ◽  
...  
Keyword(s):  
Phosphorus Ylides ◽  
Efficient Route ◽  
Mechanistic Investigations

X-RAY PHOTOELECTRON SPECTRA OF PHOSPHORUS YLIDES. PROBING THE PHOSPHORUS-CARBON YLIDE BOND

1974 ◽  
Vol 3 (5) ◽  
pp. 405-408 ◽  
Author(s):  
Manabu Seno ◽  
Shinji Tsuchiya ◽  
Teruzo Asahara
Keyword(s):  
Photoelectron Spectra ◽  
Phosphorus Ylides ◽  
X Ray

ChemInform Abstract: New Synthesis and Cyclopropanation of α-Phenylselanyl α,β-Unsaturated Ketones with Non-Stabilized Phosphorus Ylides.

ChemInform ◽  
2009 ◽  
Vol 40 (10) ◽  
Author(s):  
Sebastien Redon ◽  
Stephane Leleu ◽  
Xavier Pannecoucke ◽  
Xavier Franck ◽  
Francis Outurquin
Keyword(s):  
Phosphorus Ylides ◽  
Unsaturated Ketones ◽  
New Synthesis
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