ChemInform Abstract: Component Separation in NMR Imaging and Multidimensional Spectroscopy Through Global Least-Squares Analysis Based on Prior Knowledge

ChemInform ◽  
2010 ◽  
Vol 30 (7) ◽  
pp. no-no
Author(s):  
Peter Stilbs
Author(s):  
Rachid Malti ◽  
Stephane Victor ◽  
Alain Oustaloup

This paper presents an up to date advances in time-domain system identification using fractional models. Both equation-error- and output-error-based models are detailed. In the former models, prior knowledge is generally used to fix differentiation orders; model coefficients are estimated using least squares. The latter models allow simultaneous estimation of model coefficients and differentiation orders using nonlinear programing. As an example, a thermal system is identified using a fractional model and is compared to a rational one.


Geophysics ◽  
2016 ◽  
Vol 81 (4) ◽  
pp. S195-S206 ◽  
Author(s):  
Mrinal Sinha ◽  
Gerard T. Schuster

Imaging seismic data with an erroneous migration velocity can lead to defocused migration images. To mitigate this problem, we first choose a reference reflector whose topography is well-known from the well logs, for example. Reflections from this reference layer are correlated with the traces associated with reflections from deeper interfaces to get crosscorrelograms. Interferometric least-squares migration (ILSM) is then used to get the migration image that maximizes the crosscorrelation between the observed and the predicted crosscorrelograms. Deeper reference reflectors are used to image deeper parts of the subsurface with a greater accuracy. Results on synthetic and field data show that defocusing caused by velocity errors is largely suppressed by ILSM. We have also determined that ILSM can be used for 4D surveys in which environmental conditions and acquisition parameters are significantly different from one survey to the next. The limitations of ILSM are that it requires prior knowledge of a reference reflector in the subsurface and the velocity model below the reference reflector should be accurate.


1979 ◽  
Vol 49 ◽  
pp. 287-290
Author(s):  
C.R. Subrahmanya

An optimum solution to a deconvolution problem has to fulfil three general criteria: (a) an explicit recognition of the smoothing nature of convolution; (b) a statistical treatment of noise, e.g., using the least-squares criterion; and (c) requiring the solution to conform to all our prior knowledge about it. In the usual least-squares method, one minimises a variance of ‘residuals’, or the departures of the observed data from the values expected according to the recovered solution. However, this condition does not lead to a stable solution in the case of deconvolution, since the only stable solutions are those conforming to a criterion of ‘regularisation’ or smoothness (see, e.g., Tikhonov and Arsenin 1977). In our method, the stability is achieved by minimising the variance of the second-differences of the solution simultaneously with the fulfilment of the least-squares criterion. Such a procedure was first used by Phillips(1962). However, the solution thus obtained is still unsatisfactory since it usually does not conform to oura prioriinformation. When we seek the brightness distribution of an object, the most frequent violation of our prior knowledge is that of positiveness. This motivated us to develop an Optimum Deconvolution Method (ODM) which constrains the solution to satisfy prior knowledge while retaining the features of least-squares and smoothness criteria.


1986 ◽  
Vol 234 (1) ◽  
pp. 21-29 ◽  
Author(s):  
A Cornish-Bowden ◽  
L Endrenyi

A method described previously [Cornish-Bowden & Endrenyi (1981) Biochem. J. 193, 1005-1008] for fitting theoretical equations to enzyme kinetic data without prior knowledge of weights or error distribution has been tested by computer simulation. With the equations for various kinds of linear inhibition as an example, the method performed well under all of the conditions examined, giving results that were often much better than those given by widely used least-squares alternatives, and were never appreciably worse. Although equations for two-substrate kinetics were not explicitly tested, the results for inhibition equations can be generalized to include two-substrate equations because the two are formally equivalent for simulation purposes. As a check on the results with inhibition equations the method was also tested for fitting bell-shaped pH-activity profiles and gave correspondingly good results.


Navigation ◽  
2017 ◽  
Vol 64 (1) ◽  
pp. 75-91 ◽  
Author(s):  
Mounir Adjrad ◽  
Paul D. Groves

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