An Easy and Efficient Method for the Synthesis of Hydroximoyl Chloride from Nitro Olefin and Silyl Enol Ether.

ChemInform ◽  
2003 ◽  
Vol 34 (3) ◽  
Author(s):  
Ming-Chung Yan ◽  
Zhijay Tu ◽  
Chunchi Lin ◽  
Ching-Fa Yao
Keyword(s):  
Efficient Method ◽  
Enol Ether ◽  
Silyl Enol Ether

An easy and efficient method for the synthesis of hydroximoyl chloride from nitro olefin and silyl enol ether

2002 ◽  
Vol 43 (44) ◽  
pp. 7991-7994 ◽  
Author(s):  
Ming-Chung Yan ◽  
Zhijay Tu ◽  
Chunchi Lin ◽  
Ching-Fa Yao
Keyword(s):  
Efficient Method ◽  
Enol Ether ◽  
Silyl Enol Ether

scholarly journals A Convenient Approach towards the Synthesis of ADMDP Type Iminosugars and Nojirimycin Derivatives from Sugar-Derived Lactams

Molecules ◽  
2021 ◽  
Vol 26 (18) ◽  
pp. 5459
Author(s):  
Piotr Szcześniak ◽  
Barbara Grzeszczyk ◽  
Bartłomiej Furman
Keyword(s):  
Efficient Method ◽  
Nucleophilic Addition ◽  
Diffusion Control ◽  
Partial Reduction ◽  
Enol Ether ◽  
Control Models ◽  
Silyl Enol Ether ◽  
Convenient Approach

An efficient method for the synthesis of nojirimycin- and pyrrolidine-based iminosugar derivatives has been developed. The strategy is based on the partial reduction in sugar-derived lactams by Schwartz’s reagent and tandem stereoselective nucleophilic addition of cyanide or a silyl enol ether dictated by Woerpel’s or diffusion control models, which affords amino-modified iminosugars, such as ADMDP or higher nojirimycin derivatives.

Synthesis of α-Arylcarboxylic Acid Amides from Silyl Enol Ether via Migratory Amidation with 2-Azido-1,3-dimethylimidazolinium Hexafluorophosphate

2013 ◽  
Vol 42 (7) ◽  
pp. 691-693 ◽  
Author(s):  
Mitsuru Kitamura ◽  
Kento Murakami ◽  
Yuichiro Shiratake ◽  
Tatsuo Okauchi
Keyword(s):  
Enol Ether ◽  
Silyl Enol Ether

Carbon-carbon bond formation in reactions of PhIO.cntdot.HBF4-silyl enol ether adduct with alkenes or silyl enol ethers

1989 ◽  
Vol 54 (11) ◽  
pp. 2605-2608 ◽  
Author(s):  
V. V. Zhdankin ◽  
M. Mullikin ◽  
Rik Tykwinski ◽  
Bruce Berglund ◽  
Ronald Caple ◽  
...  
Keyword(s):  
Bond Formation ◽  
Enol Ether ◽  
Enol Ethers ◽  
Carbon Bond ◽  
Silyl Enol Ethers ◽  
Carbon Carbon Bond ◽  
Silyl Enol Ether

An Access to Highly Enantioenriched cis-3,5-Disubstituted γ-Lactones from α-Bromoacetate and Silyl Enol Ether

2021 ◽  
Author(s):  
Ha Rim Lee ◽  
Seo Yun Kim ◽  
Min Ji Park ◽  
Yong Sun Park
Keyword(s):  
Nucleophilic Substitution ◽  
Enol Ether ◽  
Enol Ethers ◽  
Silyl Enol Ethers ◽  
Synthetic Strategy ◽  
Silyl Enol Ether

A novel synthetic strategy for highly enantioenriched cis-3,5-disubstituted γ-lactones has been developed by the AgOTf-promoted nucleophilic substitution of α-bromoacetates with silyl enol ethers and subsequent reductive lactonization. The utility of...

Silyl Enol Ether Based Nucleophiles

2012 ◽  
pp. 1
Author(s):  
D. W. C. MacMillan ◽  
A. J. B. Watson
Keyword(s):  
Enol Ether ◽  
Silyl Enol Ether
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