High Temperature—High Pressure Synthesis and Crystal Structure of the Incommensurately Modulated, α-PbO2 Related, Compound MnTa2O6.

ChemInform ◽  
2003 ◽  
Vol 34 (44) ◽  
Author(s):  
Nadezhda V. Tarakina ◽  
Alexander P. Tyutyunnik ◽  
Vladimir G. Zubkov ◽  
Tatjana V. D'Yachkova ◽  
Yury G. Zainulin ◽  
...  
ChemInform ◽  
2003 ◽  
Vol 34 (32) ◽  
Author(s):  
Nadezhda V. Tarakina ◽  
Alexander P. Tyutyunnik ◽  
Vladimir G. Zubkov ◽  
Tatjana V. D'yachkova ◽  
Yury G. Zainulin ◽  
...  

2003 ◽  
Vol 5 (7) ◽  
pp. 983-994 ◽  
Author(s):  
Nadezhda V. Tarakina ◽  
Alexander P. Tyutyunnik ◽  
Vladimir G. Zubkov ◽  
Tatjana V. D'Yachkova ◽  
Yury G. Zainulin ◽  
...  

2003 ◽  
Vol 5 (3) ◽  
pp. 459-463 ◽  
Author(s):  
Nadezhda V. Tarakina ◽  
Alexander P. Tyutyunnik ◽  
Vladimir G. Zubkov ◽  
Tatjana V. D'yachkova ◽  
Yury G. Zainulin ◽  
...  

2019 ◽  
Vol 74 (4) ◽  
pp. 357-363
Author(s):  
Daniela Vitzthum ◽  
Hubert Huppertz

AbstractThe mixed cation triel borate Ga4In4B15O33(OH)3 was synthesized in a Walker-type multianvil apparatus at high-pressure/high-temperature conditions of 12.5 GPa and 1300°C. Although the product could not be reproduced in further experiments, its crystal structure could be reliably determined via single-crystal X-ray diffraction data. Ga4In4B15O33(OH)3 crystallizes in the tetragonal space group I41/a (origin choice 2) with the lattice parameters a = 11.382(2), c = 15.244(2) Å, and V = 1974.9(4) Å3. The structure of the quaternary triel borate consists of a complex network of BO4 tetrahedra, edge-sharing InO6 octahedra in dinuclear units, and very dense edge-sharing GaO6 octahedra in tetranuclear units.


2014 ◽  
Vol 104 (16) ◽  
pp. 162603 ◽  
Author(s):  
M. A. Susner ◽  
S. D. Bohnenstiehl ◽  
S. A. Dregia ◽  
M. D. Sumption ◽  
Y. Yang ◽  
...  

1989 ◽  
Vol 137 (4-5) ◽  
pp. 205-206 ◽  
Author(s):  
A.W. Webb ◽  
E.F. Skelton ◽  
S.B. Qadri ◽  
E.R. Carpenter ◽  
M.S. Osofsky ◽  
...  

CrystEngComm ◽  
2021 ◽  
Author(s):  
Sergey V. Rashchenko ◽  
Anton Shatskiy ◽  
Mark Ignatov ◽  
Anton V. Arefiev ◽  
Konstantin Litasov

A new non-centrosymmetric K2Ca3(CO3)4 crystal (P212121, a = 7.39134(18) Å, b = 8.8153(2) Å, c = 16.4803(4) Å) was synthesized in multianvil press at a pressure of 3 GPa and...


2018 ◽  
Vol 74 (2) ◽  
pp. 120-124 ◽  
Author(s):  
Daisuke Urushihara ◽  
Toru Asaka ◽  
Koichiro Fukuda ◽  
Hiroya Sakurai

The strontium tungstate compound Sr3W2O9 was prepared by a high-pressure synthesis technique. The crystal structure was determined by single-crystal X-ray diffraction and transmission electron microscopy. The structure was found to be a hettotype structure of the high-pressure phase of Ba3W2O9, which has corner-sharing octahedra with a trigonal symmetry. Sr3W2O9 has a monoclinic unit cell of C2/c symmetry. One characteristic of the structure is the breaking of the threefold rotation symmetry existing in the high-pressure phase of Ba3W2O9. The substitution of Sr at the Ba site results in a significant shortening of the interlayer distances of the [AO3] layers (A = Ba, Sr) and causes a distortion in the crystal structure. In Sr3W2O9, there is an off-centre displacement of W6+ ions in the WO6 octahedra. Such a displacement is also observed in the high-pressure phase of Ba3W2O9.


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