The First Behind-Casing Fiber-Optic Installation in a High-Pressure High-Temperature Deep Gas Well in Oman

This paper discusses the first fiber-optic (FO) installation in a vertical high-pressure high-temperature deep gas well in PDO, Oman. A specially designed fiber-optic cable was successfully installed and cemented behind the production casing, which was subsequently perforated in an oriented manner without damaging the cable. This paper also describes how the fiber-optic cable was used afterwards to acquire Distributed Acoustic Sensing (DAS) and Distributed Temperature Sensing (DTS) data for the purpose of hydraulic fracturing diagnostics. Fiber-optic surveillance is becoming an increasingly important activity for well and reservoir surveillance. The added complexity of the fiber-optic installation will affect the well design, which is one of the elements that requires focused attention, especially when the fiber is installed behind casing. The impact on casing design, wellhead design, perforation strategy, and logging requirements will all be discussed. In order for a well to be completed with a permanent fiber-optic cable, a few critical procedures need to be followed, including: –modifying the wellhead design to include feedthrough ports for the cable;–optimizing the cement design;–imposing strict procedures to ensure the cable is installed behind the casing without getting stuck;–changing the perforation phasing to avoid damaging the cable;–mapping the location of the cable to allow the gun string to be oriented away from the cable. The fiber-optic cable itself needed to be designed to be protected in such a way that it would not be damaged during installation and completion (perf/frac) activities. Furthermore, the cable was also optimized to improve its detectability, to aid the oriented perforation. In deep gas wells, much more than in conventional shallow water injectors or oil producers, the well integrity aspect should be given special attention. Specifically, any risks related to unwanted gas leaks, either through the control line, poor cement, or because of other design errors should be avoided. In deep gas wells, high temperature and pressure will also play a big role in the expected lifespan of the cable. Finally, the well was hydraulically fractured in four stages, using the "plug-and-perf" technique, during which DAS and DTS data were acquired continuously and across all depths of the well. The data provided valuable information on the effectiveness of each of the frac stages, it could be used to analyze screen-outs and detect out-of-zone injection, and recommendations for the optimizations of future hydraulic frac designs could be derived. The fiber-optic data were also integrated with other open-hole data for improved understanding of the reservoir performance. The next step will be to acquire repeated time-lapse DAS and DTS data for production profiling, to gain more insights of how the long-term production performance is affected by the hydraulic frac operations.

Reducing Threading Dislocations of Single-Crystal Diamond via In Situ Tungsten Incorporation

A lower dislocation density substrate is essential for realizing high performance in single-crystal diamond electronic devices. The in-situ tungsten-incorporated homoepitaxial diamond by introducing tungsten hexacarbonyl has been proposed. A 3 × 3 × 0.5 mm3 high-pressure, high-temperature (001) diamond substrate was cut into four pieces with controlled experiments. The deposition of tungsten-incorporated diamond changed the atomic arrangement of the original diamond defects so that the propagation of internal dislocations could be inhibited. The SEM images showed that the etching pits density was significantly decreased from 2.8 × 105 cm−2 to 2.5 × 103 cm−2. The reduction of XRD and Raman spectroscopy FWHM proved that the double-layer tungsten-incorporated diamond has a significant effect on improving the crystal quality of diamond bulk. These results show the evident impact of in situ tungsten-incorporated growth on improving crystal quality and inhibiting the dislocations propagation of homoepitaxial diamond, which is of importance for high-quality diamond growth.

Effect of pressure on the phase transformations and mechanical properties of 10 mol% Mg-PSZ sintered by HPHT

MgO (10 mol%)-stabilized zirconia ceramics were obtained using high-pressure high-temperature (HPHT) sintering. The effects of the sintering pressure (2.5, 3.7, and 5.0 GPa) on the phase transformations and hardness were...

Single-Crystal Structure of HP-Sc2TeO6 Prepared by High-Pressure/High-Temperature Synthesis

The first high-pressure scandium tellurate HP-Sc2TeO6 was synthesized from an NP-Sc2TeO6 normal-pressure precursor at 12 GPa and 1173 K using a multianvil apparatus (1000 t press, Walker-type module). The compound crystallizes in the monoclinic space group P2/c (no. 13) with a = 729.43(3), b = 512.52(2), c = 1095.02(4) pm and β = 103.88(1)°. The structure was refined from X-ray single-crystal diffractometer data: R1 = 0.0261, wR2 = 0.0344, 568 F2 values and 84 variables. HP-Sc2TeO6 is isostructural to Yb2WO6 and is built up from TeO6 octahedra, typical for tellurate(VI) compounds. During synthesis, a reconstructive transition from P321 (normal-pressure modification) to P2/c (high-pressure modification) takes place and the scandium–oxygen distances as well as the coordination number of scandium increase. However, the coordination sphere around the Te6+ cations gets only slightly distorted. High-temperature powder XRD investigations revealed a back-transformation of HP-Sc2TeO6 to the ambient-pressure modification above 973 K.

High Performance Tailored Mechanically Enhanced Cement Slurry Helped in Delivering Dependable Barriers Across HPHT Reservoir: Case Study from UAE Offshore

The concept of zonal isolation has evolved recently addressing new industry challenges to provide dependable barriers throughout the life of the well. This helps ensure long term well integrity for safer and more efficient hydrocarbon production, especially for the fields predicted to have a long lifetime. This leads to tailoring of cement slurry designs for superior mechanical parameters to avoid deteriorating them under post cementing operational loads. Following cementing best practices is a key parameter to achieve a successful cementing job, however adequate mechanical properties will help a cement slurry to withstand all the cyclic loads that the well will experience during its lifetime. Determining these properties and tailoring cement slurry designs to meet these properties will help ensure that the cement slurry will still survive these loads, all the way from placement until it has experienced all the post cementing operational loads including but not limited to multiple pressure testing, unloading the well, perforations, various thermal loads during well production, hydraulic fracturing etc. The tailored cement slurry was able to provide an adequate solution of such challenges faced by an operator in Offshore UAE under a high pressure – high temperature (HPHT) environment. Stress modelling was performed for the life of the well considering post cementing operations. This helped in determining optimum mechanical properties required for the cement slurries considered. Specialized testing was performed in both lab and yard to achieve such properties for field execution. Based on various stress and hydraulic modelling, slurries ranging from 13 to 17.5 ppg were designed and pumped successfully in the wellbore. Post cementing bond logs showed adequate placement of a tailored dependable barrier across a complete wellbore including an HPHT reservoir section. This approach can be used for wells with similar challenges around the world for long term zonal isolation.

Innovative Liner Hanger System Designed for Operational Benefits in Harsh Environments

Since the beginning of drilling for oil, improving efficiency and reducing the cost of hydrocarbon recovery have been key issues when designing a well. Since then, new methods and techniques have developed the industry. One of the most critical events in the oil and gas industry was the invention of the liner hanger. Since Liner Hangers are utilized as the primary solution to wellbore construction, they have been designed with such requirements in mind. This paper will deliver an insight to an innovation life cycle where a stakeholder collaborated together to successfully deliver, plan and complete the first 15,000 PSI, 400 °F high pressure- high temperature (HPHT) Liner Hanger designed to overcome the operational obstacles that conventional liner hangers have when deployed with Multistage Frac (MSF) completion systems but still allows for successful operations in cemented completions. This liner hanger technology has been run in different parts of the world and has proven since the beginning that with all the features included in the designed stages.

Electrochemical Ozone Generation Using Compacted High Pressure High Temperature Synthesized Boron Doped Diamond Microparticle Electrodes

Electrochemical ozone production (EOP) from water is an attractive, green technology for disinfection. Boron doped diamond (BDD) electrodes, grown by chemical vapor deposition (CVD), have been widely adopted for EOP due to their wide anodic window in water and excellent chemical and electrochemical stability. High pressure high temperature (HPHT) synthesis, an alternative growth technique used predominantly for the high-volume synthesis of nitrogen doped diamond microparticles, has been seldom employed for the production of conductive BDD electrodes. In this letter, we demonstrate, for the first time, the use of BDD electrodes fabricated from HPHT conductive BDD microparticles for EOP. The BDD microparticles are first compacted to produce freestanding solid electrodes and then laser micromachined to produce a perforated electrode. The compacted HPHT BDD microparticle electrodes are shown to exhibit high EOP, producing 2.23 ± 0.07 mg L-1 of ozone per ampere of current, at consistent levels for a continuous 20 hr period with no drop off in performance. The HPHT electrodes also achieve a reasonable current efficiency of 23%, at a current density of 770 mA cm-2.

Atomistic Evidence of Nucleation Mechanism for the Direct Graphite-to-Diamond Transformation

The direct graphite-to-diamond transformation mechanism has been a subject of intense study and remains debated concerning the initial stages of the conversion, the intermediate phases, and their transformation pathways. Here, we successfully recover samples at early conversion stage by tuning high-pressure/high-temperature conditions and reveal direct evidence supporting the nucleation-growth mechanism. Atomistic observations show that intermediate orthorhombic graphite phase mediates the growth of diamond nuclei. Furthermore, we observe that quenchable orthorhombic and rhombohedra graphite are stabilized in buckled graphite at lower temperatures. These intermediate phases are further converted into hexagonal and cubic diamond at higher temperatures following energetically favorable pathways in the order: graphite -> orthorhombic graphite -> hexagonal diamond, graphite -> orthorhombic graphite -> cubic diamond, graphite -> rhombohedra graphite -> cubic diamond. These results significantly improve our understanding of the transformation mechanism, enabling the synthesis of different high-quality forms of diamond from graphite.

Extended Downhole Protection by Preservative Biocides as Demonstrated in High Pressure, High Temperature Bioreactors

Preservative biocides are designed to control microbial growth and biogenic souring in the downhole environment. We report the prevention of biogenic souring by 4,4-dimethyloxazolidine (DMO, a preservative biocide) and glutaraldehyde as compared to that afforded by tributyl tetradecyl phosphonium chloride (TTPC, a cationic surface-active biocide), in a first-of-its kind suite of High Pressure, High Temperature (HPHT) Bioreactors that simulate hydraulically fractured shale reservoirs. The design of these new bioreactors, which recreate the downhole environment (temperatures, pressures, formation solids, and frac additives) in a controlled laboratory environment, enables the evaluation of biocides under field-relevant conditions. The bioreactors receiving either no biocide treatment or treatment with a high concentration of TTPC (50 ppm active ingredient) rapidly soured within the first two weeks of shut-in, and all surpassed the maximum detectable level of H2S (343 ppm) after the addition of live microbes to the reactors. Conversely, a higher loading of DMO (150 pppm active ingredient) maintained H2S concentrations below the minimum dectable level (5 ppm) for six weeks, and held H2S concentrations to 10.3 +/- 5.2 ppm after fifteen weeks of shut-in and two post shut-in microbial rechallenges. In a second study, a lower concentration of DMO (50 ppm active ingredient) maintained H2S concentrations below the minimum detectable level through the addition of live microbes after three weeks, and H2S concentrations only registered above 10 ppm upon a second addition of live microbes after five weeks. In this same study (which was performed at moderate temperatures), a 50 ppm (active ingredient) treatment of glutaraldehyde also maintained H2S concentrations below the minimum detectable level through the addition of live microbes after three weeks, and H2S concentrations registered 15.0 +/- 9.7 ppm H2S after four weeks. Similar time scales of protection are observed for each treatment condition through the enumeration of microbes present in each reactor. The differentiation in antimicrobial activity (and specifically, prevention of biogenic souring) afforded by DMO and glutaraldehyde suggests that such nonionic, preservative biocides are a superior choice for maintaining control over problematic microorganisms as compared to surface-active biocides like TTPC at the concentrations tested. The significant duration of efficacy provided by DMO and glutaraldehyde in this first-of-its-kind suite of simulated reservoirs demonstrates that comprehensive preservation and prevention of biogenic souring from completion through to production is feasible. Such comprehensive, prolonged protection is especially relevant for extended shut-ins or drilled but uncompleted wells (DUCS) such as those experienced during the COVID-19 pandemic. The environment simulated within the bioreactors demonstrates that the compatibility afforded by a preservative biocide offers downhole protection that cationic, surface-active biocides do not.