ChemInform Abstract: Synthesis and Crystal Structure of a New Open-Framework Iron Phosphate (NH4)4Fe3(OH)2F2 [H3(PO4)4]: Novel Linear Trimer of Corner-Sharing Fe(III) Octahedra.

ChemInform ◽  
2011 ◽  
Vol 42 (12) ◽  
pp. no-no
Author(s):  
Jin-Xiao Mi ◽  
Cheng-Xin Wang ◽  
Ning Chen ◽  
Rong Li ◽  
Yuanming Pan
1999 ◽  
Vol 9 (12) ◽  
pp. 3119-3123 ◽  
Author(s):  
Kjell Ove Kongshaug ◽  
Helmer Fjellvåg ◽  
Karl Petter Lillerud

2003 ◽  
Vol 9 (4) ◽  
pp. 856-861 ◽  
Author(s):  
Ludovic Josien ◽  
Angélique Simon-Masseron ◽  
Volker Gramlich ◽  
Joël Patarin ◽  
Loïc Rouleau

2018 ◽  
Vol 149 ◽  
pp. 01084 ◽  
Author(s):  
Ghaleb Alhakmi ◽  
Abderrazzak Assani ◽  
Mohamed Saadi ◽  
Lahcen El Ammari

Two new phosphates with alluaudite type structure (M, Mn)3Fe(PO4)3 (M= Ca, Cd), namely Ca1.54Mn1.46Fe(PO4)3 and Cd0.66Mn2.34Fe(PO4)3, has been synthesized by a solid state reaction and characterized by single-crystal X-ray diffraction. The two compounds crystallize in the monoclinic system with C2/c space group. Their open framework results from (Fe1/Mn1)2O10 units of edge-sharing (Fe/Mn)O6 octahedra, which alternate with M(1)O6 octahedra (M(1)=Ca1/Mn2 or Cd1/Mn2) that form infinite chains running along [10-1] direction. These chains are linked together through the common corners of PO4 tetrahedra giving rise to two types of tunnels occupied by bivalent cations Ca2+ or Cd2+ and Mn2+.


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