ChemInform Abstract: ZrOCl2·8H2O as a Highly Efficient, Eco-Friendly and Recyclable Lewis Acid Catalyst for One-Pot Synthesis of N-Substituted Pyrroles under Solvent-Free Conditions at Room Temperature.

ChemInform ◽  
2011 ◽  
Vol 42 (52) ◽  
pp. no-no
Author(s):  
Ali Rahmatpour
Keyword(s):  
Lewis Acid ◽  
Room Temperature ◽  
Acid Catalyst ◽  
Solvent Free ◽  
One Pot ◽  
Highly Efficient ◽  
One Pot Synthesis ◽  
Solvent Free Conditions ◽  
Lewis Acid Catalyst ◽  
Substituted Pyrroles

Antimony(III) chloride impregnated on alumina — An efficient and economical Lewis acid catalyst for one-pot synthesis of dihydropyrimidinones under solvent-free conditions

2006 ◽  
Vol 84 (3) ◽  
pp. 433-437 ◽  
Author(s):  
Kamal K Kapoor ◽  
Bilal A Ganai ◽  
Satish Kumar ◽  
Charanjeet S Andotra
Keyword(s):  
Lewis Acid ◽  
Condensation Reaction ◽  
Thermal Conditions ◽  
Acid Catalyst ◽  
Solvent Free ◽  
One Pot ◽  
One Pot Synthesis ◽  
Solvent Free Conditions ◽  
Lewis Acid Catalyst

The antimony(III) chloride impregnated on alumina efficiently catalyses a one-pot, three-component condensation reaction among an aldehyde, a β-ketoester, and urea or thiourea to afford the corresponding dihydropyrimidinones in good to excellent yields. The reactions are probed in microwave (MW), ultrasonic, and thermal conditions and the best results are found using MW under solvent-free conditions.Key words: Biginelli dihydropyrimidinones synthesis, SbCl3–Al2O3, MW, sonication, solid supported.

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