ChemInform Abstract: Reduction Reactions in Green Solvents: Water, Supercritical Carbon Dioxide, and Ionic Liquids

ChemInform ◽  
2011 ◽  
Vol 43 (1) ◽  
pp. no-no
Author(s):  
Luis Alvarez de Cienfuegos ◽  
Rafael Robles ◽  
Delia Miguel ◽  
Jose Justicia ◽  
Juan M. Cuerva
Keyword(s):  
Carbon Dioxide ◽  
Ionic Liquids ◽  
Supercritical Carbon Dioxide ◽  
Green Solvents ◽  
Reduction Reactions ◽  
Supercritical Carbon

Reduction Reactions in Green Solvents: Water, Supercritical Carbon Dioxide, and Ionic Liquids

ChemSusChem ◽  
2011 ◽  
Vol 4 (8) ◽  
pp. 1035-1048 ◽  
Author(s):  
Luis Álvarez de Cienfuegos ◽  
Rafael Robles ◽  
Delia Miguel ◽  
José Justicia ◽  
Juan M. Cuerva
Keyword(s):  
Carbon Dioxide ◽  
Ionic Liquids ◽  
Supercritical Carbon Dioxide ◽  
Green Solvents ◽  
Reduction Reactions ◽  
Supercritical Carbon

Ionic liquids and supercritical carbon dioxide: green and alternative reaction media for chemical processes

2016 ◽  
Vol 32 (6) ◽  
Author(s):  
Ruixia Liu ◽  
Peng Zhang ◽  
Suojiang Zhang ◽  
Ting Yan ◽  
Jiayu Xin ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Ionic Liquids ◽  
Supercritical Carbon Dioxide ◽  
Chemical Processes ◽  
Reaction Media ◽  
Supercritical Carbon

AbstractIonic liquids (ILs) and supercritical CO

Long term continuous chemoenzymatic dynamic kinetic resolution of rac-1-phenylethanol using ionic liquids and supercritical carbon dioxide

2009 ◽  
Vol 11 (4) ◽  
pp. 538 ◽  
Author(s):  
Pedro Lozano ◽  
Teresa De Diego ◽  
Corina Mira ◽  
Kimberley Montague ◽  
Michel Vaultier ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Ionic Liquids ◽  
Supercritical Carbon Dioxide ◽  
Kinetic Resolution ◽  
Dynamic Kinetic Resolution ◽  
Supercritical Carbon

Dynamic Kinetic Resolution of Sec-Alcohols in Ionic Liquids/Supercritical Carbon Dioxide Biphasic Systems

2009 ◽  
Vol 7 (1) ◽  
Author(s):  
Pedro Lozano ◽  
Teresa De Diego ◽  
Michel Vaultier ◽  
Jose L Iborra
Keyword(s):  
Carbon Dioxide ◽  
Ionic Liquids ◽  
Supercritical Carbon Dioxide ◽  
Kinetic Resolution ◽  
Immobilized Lipase ◽  
Enzymatic Catalysis ◽  
Chemical Properties ◽  
Dynamic Kinetic Resolution ◽  
Biphasic Systems ◽  
Supercritical Carbon

Supercritical fluids and ionic liquids are neoteric solvents that can be used as non-conventional reaction media for enzymatic catalysis under optimised conditions. These solvents exhibit many different physical and chemical properties, but have two cross-points: they are not-miscible and can be easily separated from substrates and products, and they can be reused. As supercritical carbon dioxide (scCO2) can dissolve in the ionic liquid (IL) phase (up to 0.7 mole fraction), a new concept of biphasic bioreactors for Fine Chemicals syntheses may be developed by using both enzyme and chemical catalysts "immobilized" into the IL phase, and substrates transported by the scCO2 phase. The system was tested for the continuous chemoenzymatic dynamic kinetic resolution (DKR) of rac-1-phenylethanol in IL/scCO2 by using simultaneously immobilized lipase (Novozym 435) and acid zeolites catalysts at 50°C and 100 bars, providing good yields (up 98.0 %) for R-phenylethyl propionate ester with excellent enantioselectivity (up to 97.3 %), and without any activity loss after 14 days of operation.

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