ChemInform Abstract: Suzuki-Miyaura Cross-Coupling Reactions in a Solkane365/227/Ethanol Blend at Ambient Temperature.

ChemInform ◽  
2012 ◽  
Vol 43 (30) ◽  
pp. no-no
Author(s):  
Xiu-Hua Xu ◽  
Ayaka Azuma ◽  
Akihiro Kusuda ◽  
Etsuko Tokunaga ◽  
Norio Shibata
Keyword(s):  
Ambient Temperature ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Cross Coupling Reactions

scholarly journals Practical tetrafluoroethylene fragment installation through a coupling reaction of (1,1,2,2-tetrafluorobut-3-en-1-yl)zinc bromide with various electrophiles

2018 ◽  
Vol 14 ◽  
pp. 2375-2383 ◽  
Author(s):  
Ken Tamamoto ◽  
Shigeyuki Yamada ◽  
Tsutomu Konno
Keyword(s):  
Ambient Temperature ◽  
Organic Molecules ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Zinc Bromide ◽  
Acyl Chlorides ◽  
Copper Species ◽  
Cross Coupling Reactions ◽  
Organozinc Reagent

(1,1,2,2-Tetrafluorobut-3-en-1-yl)zinc bromide was prepared by insertion of the zinc–silver couple into the CF2–Br bond of commercially available 4-bromo-3,3,4,4-tetrafluorobut-1-ene in DMF at 0 °C for 0.5 h, The resultant polyfluorinated zinc reagent was found to be thermally stable at ambient temperature and storable for at least 1.5 years in the refrigerator. This CF2CF2-containing organozinc reagent could be easily transmetallated to copper species, which underwent cross-coupling reactions with various aromatic iodides or acyl chlorides to produce a broad range of CF2CF2-containing organic molecules in good-to-excellent yields. Therefore, the zinc reagent could become a new and practical synthetic tool for producing functional molecules with a CF2CF2 fragment.

scholarly journals Palladium nanoparticles decorated into a biguanidine modified-KIT-5 mesoporous structure: a recoverable nanocatalyst for ultrasound-assisted Suzuki–Miyaura cross-coupling

RSC Advances ◽  
2019 ◽  
Vol 9 (71) ◽  
pp. 41581-41590 ◽  
Author(s):  
Hojat Veisi ◽  
Amin Mirzaei ◽  
Pourya Mohammadi
Keyword(s):  
Ambient Temperature ◽  
Palladium Nanoparticles ◽  
Research Work ◽  
Cross Coupling ◽  
Mesoporous Structure ◽  
Coupling Reactions ◽  
Ultrasound Waves ◽  
Cross Coupling Reactions ◽  
Ultrasound Assisted

In the current research work, a new KIT-5-biguanidine-Pd(0) catalyst was prepared and applied to ultrasound-assisted Suzuki–Miyaura cross-coupling reactions using ultrasound waves at ambient temperature.

Suzuki-Miyaura Cross-Coupling Reactions in a Solkane365/227/Ethanol Blend at Ambient Temperature

2012 ◽  
Vol 2012 (8) ◽  
pp. 1504-1508 ◽  
Author(s):  
Xiu-Hua Xu ◽  
Ayaka Azuma ◽  
Akihiro Kusuda ◽  
Etsuko Tokunaga ◽  
Norio Shibata
Keyword(s):  
Ambient Temperature ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Cross Coupling Reactions
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