ChemInform Abstract: One-Step Synthesis of Isocoumarins and 3-Benzylidenephthalides via Ligandless Pd-Catalyzed Oxidative Coupling of Benzoic Acids and Vinylarenes.

Facile preparation of hypercrosslinked carbazole-based porous organic polymers via FeCl3-promoted one-step oxidative coupling reaction and Friedel–Crafts alkylation from the vinyl or hydroxymethyl functionalized carbazole is reported.

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A room-temperature synthesis of 2,2′-bisoxazoles through palladium-catalyzed oxidative coupling of α-isocyanoacetamides

Organic Chemistry Frontiers ◽

10.1039/c4qo00250d ◽

2014 ◽

Vol 1 (11) ◽

pp. 1285-1288 ◽

Cited By ~ 33

Author(s):

Jian Wang ◽

Shuang Luo ◽

Jing Li ◽

Qiang Zhu

Keyword(s):

Oxidative Coupling ◽

Room Temperature ◽

Temperature Synthesis ◽

Room Temperature Synthesis ◽

Palladium Catalyzed ◽

One Step

A novel one-step synthesis of both symmetric and unsymmetric 2,2′-bisoxazoles starting from simple acyclic α-isocyanoacetamides was achieved.

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Chiral Conjoined Cavitands

Australian Journal of Chemistry ◽

10.1071/ch03299 ◽

2004 ◽

Vol 57 (4) ◽

pp. 339 ◽

Cited By ~ 3

Author(s):

Jacob L. Irwin ◽

David J. Sinclair ◽

Alison J. Edwards ◽

Michael S. Sherburn

Keyword(s):

Single Crystal ◽

1H Nmr ◽

Oxidative Coupling ◽

Higher Order ◽

New Host ◽

X Ray ◽

Conformationally Restricted ◽

Unusual Form ◽

One Step ◽

Partially Occluded

Tetrabromocavitand bowls are converted into rim-connected hexabromodimers in one step in 17–22% yields by oxidative coupling of higher order arylcuprates. 1H NMR and single crystal X-ray analyses of the rim-connected dimers reveal a conformationally restricted structure in which the rims of the two cavitand bowls describe planes angled at 78.8° to one another. Each of the two bowl cavities are occupied by a guest, in addition to being partially occluded by a portion of the complementary bowl rim. These new host compounds exhibit a very unusual form of enantioisomerism.

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Homogeneous, catalytic, oxidative coupling of methane to acetic acid in one step

Topics in Catalysis ◽

10.1007/s11244-005-2887-4 ◽

2005 ◽

Vol 32 (3-4) ◽

pp. 169-174 ◽

Cited By ~ 13

Author(s):

Roy A. Periana ◽

Oleg Mironov ◽

Doug Taube ◽

Gaurav Bhalla ◽

C. J. Jones

Keyword(s):

Acetic Acid ◽

Oxidative Coupling ◽

Oxidative Coupling Of Methane ◽

One Step

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An Efficient Waste-Free Oxidative Coupling via Regioselective C—H Bond Cleavage: Rh/Cu-Catalyzed Reaction of Benzoic Acids with Alkynes and Acrylates under Air.

ChemInform ◽

10.1002/chin.200733129 ◽

2007 ◽

Vol 38 (33) ◽

Author(s):

Kenji Ueura ◽

Tetsuya Satoh ◽

Masahiro Miura

Keyword(s):

Oxidative Coupling ◽

Bond Cleavage ◽

Benzoic Acids

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Rhodium- and iridium-catalyzed oxidative coupling of benzoic acids with alkynes and alkenes

Pure and Applied Chemistry ◽

10.1351/pac200880051127 ◽

2008 ◽

Vol 80 (5) ◽

pp. 1127-1134 ◽

Cited By ~ 63

Author(s):

Tetsuya Satoh ◽

Kenji Ueura ◽

Masahiro Miura

Keyword(s):

Oxidative Coupling ◽

Benzoic Acids ◽

Naphthalene Derivatives ◽

Rh Catalyst

The oxidative coupling of benzoic acids with alkynes and alkenes effectively proceeds in the presence of a Rh catalyst and an appropriate oxidant to produce the corresponding isocoumarin and phthalide derivatives, respectively. Interestingly, by using an Ir catalyst in place of Rh, the acids and alkynes undergo 1:2 coupling accompanied by decarboxylation to afford naphthalene derivatives exclusively.

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