ChemInform Abstract: Transition-Metal-Catalyzed Laboratory-Scale Carbon-Carbon Bond-Forming Reactions of Ethylene

ChemInform ◽  
2014 ◽  
Vol 45 (6) ◽  
pp. no-no
Author(s):  
Vaneet Saini ◽  
Benjamin J. Stokes ◽  
Matthew S. Sigman
Keyword(s):  
Transition Metal ◽  
Laboratory Scale ◽  
Carbon Bond ◽  
Bond Forming ◽  
Carbon Carbon Bond ◽  
Bond Forming Reactions ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

scholarly journals Applications of 4,4′-(Me3Si)2-BINAP in Transition-Metal-Catalyzed Asymmetric Carbon—Carbon Bond-Forming Reactions.

ChemInform ◽  
2005 ◽  
Vol 36 (45) ◽  
Author(s):  
Masamichi Ogasawara ◽  
Helen L. Ngo ◽  
Takeshi Sakamoto ◽  
Tamotsu Takahashi ◽  
Wenbin Lin
Keyword(s):  
Transition Metal ◽  
Carbon Bond ◽  
Bond Forming ◽  
Carbon Carbon Bond ◽  
Bond Forming Reactions ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed ◽  
Asymmetric Carbon

Applications of 4,4‘-(Me3Si)2-BINAP in Transition-Metal-Catalyzed Asymmetric Carbon−Carbon Bond-Forming Reactions

2005 ◽  
Vol 7 (14) ◽  
pp. 2881-2884 ◽  
Author(s):  
Masamichi Ogasawara ◽  
Helen L. Ngo ◽  
Takeshi Sakamoto ◽  
Tamotsu Takahashi ◽  
Wenbin Lin
Keyword(s):  
Transition Metal ◽  
Carbon Bond ◽  
Bond Forming ◽  
Carbon Carbon Bond ◽  
Bond Forming Reactions ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed ◽  
Asymmetric Carbon

Transition-metal-catalyzed carbon-carbon bond forming reactions: regio- and chemoselective iron(0)-catalyzed diene to olefin cross-coupling reactions

1986 ◽  
Vol 5 (11) ◽  
pp. 2395-2398 ◽  
Author(s):  
James M. Takacs ◽  
Lawrence G. Anderson ◽  
G. V. Bindu. Madhavan ◽  
Mark W. Creswell ◽  
Franklin L. Seely ◽  
...  
Keyword(s):  
Transition Metal ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Carbon Bond ◽  
Bond Forming ◽  
Cross Coupling Reactions ◽  
Carbon Carbon Bond ◽  
Bond Forming Reactions ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

scholarly journals Transition Metal-Catalyzed α-Position Carbon–Carbon Bond Formations of Carbonyl Derivatives

Catalysts ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 861 ◽  
Author(s):  
Ha-Eun Lee ◽  
Dopil Kim ◽  
Ahrom You ◽  
Myung Hwan Park ◽  
Min Kim ◽  
...  
Keyword(s):  
Transition Metal ◽  
Carbonyl Compounds ◽  
Bond Formation ◽  
Chiral Ligand ◽  
Catalytic Systems ◽  
Carbon Bond ◽  
Carbonyl Derivatives ◽  
Carbon Carbon Bond ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

α-Functionalization of carbonyl compounds in organic synthesis has traditionally been accomplished via classical enolate chemistry. As α-functionalized carbonyl moieties are ubiquitous in biologically and pharmaceutically valuable molecules, catalytic α-alkylations have been extensively studied, yielding a plethora of practical and efficient methodologies. Moreover, stereoselective carbon–carbon bond formation at the α-position of achiral carbonyl compounds has been achieved by using various transition metal–chiral ligand complexes. This review describes recent advances—in the last 20 years and especially focusing on the last 10 years—in transition metal-catalyzed α-alkylations of carbonyl compounds, such as aldehydes, ketones, imines, esters, and amides and in efficient carbon–carbon bond formations. Active catalytic species and ligand design are discussed, and mechanistic insights are presented. In addition, recently developed photo-redox catalytic systems for α-alkylations are described as a versatile synthetic tool for the synthesis of chiral carbonyl-bearing molecules.

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