ChemInform Abstract: New Bis(imino)pyridine Complexes of Iron(II) and Iron(III), and Their Catalytic Activity in the Mukaiyama Aldol Reaction.

ChemInform ◽  
2014 ◽  
Vol 45 (25) ◽  
pp. no-no ◽  
Author(s):  
Pushkar Shejwalkar ◽  
Nigam P. Rath ◽  
Eike B. Bauer
Keyword(s):  
Catalytic Activity ◽  
Aldol Reaction ◽  
Mukaiyama Aldol Reaction ◽  
Pyridine Complexes ◽  
Mukaiyama Aldol

ChemInform Abstract: New Indenyl Phosphinooxazoline Complexes of Iron and Their Catalytic Activity in the Mukaiyama Aldol Reaction.

ChemInform ◽  
2010 ◽  
Vol 41 (35) ◽  
pp. no-no
Author(s):  
Matthew Lenze ◽  
Sergey L. Sedinkin ◽  
Nigam P. Rath ◽  
Eike B. Bauer
Keyword(s):  
Catalytic Activity ◽  
Aldol Reaction ◽  
Mukaiyama Aldol Reaction ◽  
Mukaiyama Aldol

New indenyl phosphinooxazoline complexes of iron and their catalytic activity in the Mukaiyama aldol reaction

2010 ◽  
Vol 51 (21) ◽  
pp. 2855-2858 ◽  
Author(s):  
Matthew Lenze ◽  
Sergey L. Sedinkin ◽  
Nigam P. Rath ◽  
Eike B. Bauer
Keyword(s):  
Catalytic Activity ◽  
Aldol Reaction ◽  
Mukaiyama Aldol Reaction ◽  
Mukaiyama Aldol

Mukaiyama Aldol Reaction Catalyzed by (Benz)imidazolium-Based Halogen Bond Donors

2020 ◽  
Author(s):  
Revannath L. Sutar ◽  
Nikita Erochok ◽  
Stefan Huber
Keyword(s):  
Halogen Bond ◽  
Aldol Reaction ◽  
Mukaiyama Aldol Reaction ◽  
Mukaiyama Aldol ◽  
Background Reaction ◽  
Strong Performance ◽  
The Stability ◽  
Elemental Iodine

A series of cationic monodentate and bidentate iodo(benz)­imidazolium-based halogen bond (XB) donors were employed as catalysts in a Mukaiyama aldol reaction. While 5 mol% of a monodentate variant showed noticeable activity, a <i>syn</i>-preorganized bidentate XB donor provided a strong performance even with 0.5 mol% loading. In contrast to the very active BAr<sup>F</sup><sub>4</sub> salts, PF<sub>6</sub> or OTf salts were either inactive or showed background reaction. Repetition experiments clearly ruled out a potential hidden catalysis by elemental iodine and demonstrated the stability of our catalyst over three consecutive cycles.

ChemInform Abstract: Mukaiyama Aldol Reaction of Trimethylsilyl Enolate with Aldehyde Catalyzed by CuI.

ChemInform ◽  
2013 ◽  
Vol 44 (22) ◽  
pp. no-no
Author(s):  
Hima Rani Kalita ◽  
Arun Jyoti Borah ◽  
Prodeep Phukan
Keyword(s):  
Aldol Reaction ◽  
Mukaiyama Aldol Reaction ◽  
Mukaiyama Aldol
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