ChemInform Abstract: Microwave-Assisted Synthesis of Novel Perimidinium Salts as N-Heterocyclic Carbene Precursors: Involvement in Palladium-Catalyzed Cross-Coupling Reactions.

Cross-coupling reactions furnishing carbon–carbon (C–C) bond is one of the most challenging tasks in organic syntheses. The early developed reaction protocols by Negishi, Heck, Kumada, Sonogashira, Stille, Suzuki, and Hiyama, utilizing palladium or its salts as catalysis have, for decades, attracted and inspired researchers affiliated with academia and industry. Tremendous efforts have been paid to develop and achieve more sustainable reaction conditions, such as the reduction in energy consumption by applying the microwave irradiation technique. Chemical reactions under controlled microwave conditions dramatically reduce the reaction time and therefore resulting in increase in the yield of the desired product by minimizing the formation of side products. In this review, we mainly focus on the recent advances and applications of palladium catalyzed cross-coupling carbon–carbon bond formation under microwave technology.

Download Full-text

Efficient Microwave-Assisted Palladium-Catalyzed Suzuki-Miyaura Cross-Coupling Reactions in 5-Nitroimidazole Series

Synthesis ◽

10.1055/s-0029-1216905 ◽

2009 ◽

Vol 2009 (18) ◽

pp. 3150-3156

Author(s):

Patrice Vanelle ◽

Maxime Crozet ◽

Laura Zink ◽

Vincent Remusat ◽

Christophe Curti

Keyword(s):

Cross Coupling ◽

Coupling Reactions ◽

Microwave Assisted ◽

Cross Coupling Reactions ◽

Palladium Catalyzed

Download Full-text

ChemInform Abstract: Microwave-Assisted Synthesis of Novel Perimidinium Salts as N-Heterocyclic Carbene Precursors: Involvement in Palladium-Catalyzed Cross-Coupling Reactions.

Microwave-Assisted Synthesis of Novel Perimidinium Salts as N-Heterocyclic Carbene Precursors: Involvement in Palladium-Catalyzed Cross-Coupling Reactions

Microwave-assisted synthesis of Pd nanoparticles and their catalysis application for Suzuki cross-coupling reactions

Microwave-assisted palladium-catalyzed cross-coupling reactions between pyranoid glycals and aryl bromides. Synthesis of 2′-deoxy C-aryl-β-glycopyranosides

Microwave-assisted Synthesis of a 3-Aminoimidazo[1,2-a]-pyridine/pyrazine Library by Fluorous Multicomponent Reactions and Subsequent Cross-coupling Reactions

ChemInform Abstract: Microwave-Assisted Palladium-Catalyzed Cross-Coupling Reactions Between Pyranoid Glycals and Aryl Bromides. Synthesis of 2â²-Deoxy C-Aryl-Î²-glycopyranosides.

ChemInform Abstract: Modular Synthesis of Biaryl-Substituted Phosphine Ligands: Application in Microwave-Assisted Palladium-Catalyzed C-N Cross-Coupling Reactions.

Modular Synthesis of Biaryl-Substituted Phosphine Ligands: Application in Microwave-Assisted Palladium-Catalyzed C-N Cross-Coupling Reactions

Microwave-assisted synthesis of palladium nanoparticles supported on graphene: A highly active and recyclable catalyst for carbon–carbon cross-coupling reactions

Microwave-Assisted Palladium-Catalyzed Cross-Coupling Reactions: Generation of Carbon–Carbon Bond

Efficient Microwave-Assisted Palladium-Catalyzed Suzuki-Miyaura Cross-Coupling Reactions in 5-Nitroimidazole Series

ChemInform Abstract: Microwave-Assisted Palladium-Catalyzed Cross-Coupling Reactions Between Pyranoid Glycals and Aryl Bromides. Synthesis of 2â²-Deoxy C-Aryl-Î²-glycopyranosides.