ChemInform Abstract: An Efficient Route to Regioselective Functionalization of Benzo[b]thiophenes via Palladium-Catalyzed Decarboxylative Heck Coupling Reactions: Insights from Experiment and Computation.

ChemInform ◽  
2016 ◽  
Vol 47 (20) ◽  
Author(s):  
Daoshan Yang ◽  
Yuxia Liu ◽  
Pengfei Sun ◽  
Ning Zhang ◽  
Wei Wei ◽  
...  
Keyword(s):  
Coupling Reactions ◽  
Heck Coupling ◽  
Palladium Catalyzed ◽  
Efficient Route ◽  
Regioselective Functionalization

An efficient route to regioselective functionalization of benzo[b]thiophenes via palladium-catalyzed decarboxylative Heck coupling reactions: insights from experiment and computation

2016 ◽  
Vol 14 (3) ◽  
pp. 895-904 ◽  
Author(s):  
Daoshan Yang ◽  
Yuxia Liu ◽  
Pengfei Sun ◽  
Ning Zhang ◽  
Wei Wei ◽  
...  
Keyword(s):  
Carboxylic Acids ◽  
Coupling Reactions ◽  
Heck Coupling ◽  
Palladium Catalyzed ◽  
Efficient Route ◽  
Type Coupling ◽  
Regioselective Functionalization

This study reports the Pd-catalyzed decarboxylative Heck-type coupling of 3-chlorobenzo[b]thiophene-2-carboxylic acids with styrenes.

The Synthesis of Novel Oligomer 4,8-Di(4-hexyl-2-thienyl)-2λ4δ2-Benzo[1,2-c;4,5-c’]bis[1,2,5]-Thiadiazole

2012 ◽  
Vol 602-604 ◽  
pp. 696-699
Author(s):  
Xiao Xiao Zhuang ◽  
Xiao Long Lei ◽  
Xiao Xia Sun
Keyword(s):  
Side Chains ◽  
Coupling Reactions ◽  
Low Bandgap ◽  
Palladium Catalyzed ◽  
Efficient Route ◽  
High Yields ◽  
Bandgap Materials

Heterocyclic oligomer based on BBT bearing solubilizing side chains have been synthesized in high yields over six steps from readily available starting materials. This approach offers a much milder, shorter, and more efficient route to BBT derivatives than current methods. This unit can then be used in the synthesis of low bandgap materials via palladium-catalyzed coupling reactions.

Palladium-catalyzed Mizoroki–Heck coupling reactions using sterically bulky phosphite ligand

2010 ◽  
Vol 13 (11) ◽  
pp. 1329-1331 ◽  
Author(s):  
Eunhye Jung ◽  
Kyungho Park ◽  
Jaewook Kim ◽  
Hee-Tae Jung ◽  
Il-Kwon Oh ◽  
...  
Keyword(s):  
Coupling Reactions ◽  
Heck Coupling ◽  
Palladium Catalyzed

scholarly journals Palladium-Catalyzed Desulfitative Mizoroki-Heck Coupling Reactions of Sulfonyl Chlorides with Olefins in a Nitrile-Functionalized Ionic Liquid

Synlett ◽  
2006 ◽  
Vol 2006 (18) ◽  
pp. 3155-3157 ◽  
Author(s):  
Paul Dyson ◽  
Pierre Vogel ◽  
Srinivas Reddy Dubbaka ◽  
Dongbin Zhao ◽  
Zhaofu Fei ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Coupling Reactions ◽  
Heck Coupling ◽  
Sulfonyl Chlorides ◽  
Functionalized Ionic Liquid ◽  
Palladium Catalyzed
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