Conformational Equilibria of 2‐Methoxypyridine⋅⋅⋅CO 2 : Cooperative and Competitive Tetrel and Weak Hydrogen Bonds

ChemPhysChem ◽  
2020 ◽  
Author(s):  
Wanying Cheng ◽  
Yang Zheng ◽  
Sven Herbers ◽  
Huaili Zheng ◽  
Qian Gou
1978 ◽  
Vol 47 ◽  
pp. 285-290 ◽  
Author(s):  
J.P. Perchard ◽  
C. Perchard ◽  
A. Burneau ◽  
J. Limouzi

CrystEngComm ◽  
2012 ◽  
Vol 14 (1) ◽  
pp. 178-187 ◽  
Author(s):  
Carl-Johan Wallentin ◽  
Edvinas Orentas ◽  
Magnus T. Johnson ◽  
Nikoletta B. Báthori ◽  
Eugenijus Butkus ◽  
...  

2013 ◽  
Vol 2 (6) ◽  
pp. 343-346 ◽  
Author(s):  
Francisco Sánchez-Viesca ◽  
Fernando Cortés ◽  
Reina Gómez ◽  
Martha Berros

IUCrData ◽  
2020 ◽  
Vol 5 (10) ◽  
Author(s):  
Rafael A. Adrian ◽  
Diego R. Hernandez ◽  
Hadi D. Arman

The central copper(II) atom of the title salt, {[Cu(CF3SO3)(CH3CN)2(C12H12N2O2)](CF3SO3)} n or [[Cu(CH3CN)2(diOMe-bpy)(CF3SO3)](CF3SO3)] n where diOMe-bpy is 4,4′-dimethoxy-2,2′-bipyridine, C12H12N2O2, is sixfold coordinated by the N atoms of the chelating bipyridine ligand, the N atoms of two acetonitrile molecules, and two trifluoromethanesulfonate O atoms in a tetragonally distorted octahedral shape. The formation of polymeric chains [Cu(CH3CN)2(diOMe-bpy)(CF3SO3)]+ n leaves voids for the non-coordinating trifluoromethanesulfonate anions that interact with the complex through weak hydrogen bonds. The presence of weakly coordinating ligands like acetonitrile and trifluoromethanesulfonate makes the title compound a convenient starting material for the synthesis of novel metal–organic frameworks.


2011 ◽  
Vol 67 (a1) ◽  
pp. C388-C389
Author(s):  
C. A. Jiménez ◽  
N. Parra ◽  
P. I. Hidalgo ◽  
J. Belmar ◽  
J. Pasán ◽  
...  

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