Hydroxyapatite‐Supported Polyoxometalates for the Highly Selective Aerobic Oxidation of 5‐Hydroxymethylfurfural or Glucose to 2,5‐Diformylfuran under Atmospheric Pressure

A magnetic Co-based heterogeneous catalyst derived from MOFs is highly efficient in selective oxidation of alcohols in neat water under an atmospheric pressure of air and base-free conditions.

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Spatial separation of dual-cocatalysts on bismuth vanadate for selective aerobic oxidation of benzylalcohols to benzaldehydes under visible light irradiation

Catalysis Science & Technology ◽

10.1039/c8cy01778f ◽

2018 ◽

Vol 8 (23) ◽

pp. 6173-6179 ◽

Cited By ~ 4

Author(s):

Xu Jin ◽

Rengui Li ◽

Yue Zhao ◽

Xiaodan Liu ◽

Xiaoqi Wang ◽

...

Keyword(s):

Visible Light ◽

Visible Light Irradiation ◽

Aerobic Oxidation ◽

Spatial Separation ◽

Bismuth Vanadate ◽

Light Irradiation ◽

Selective Aerobic Oxidation

Efficient converting of alcohols to aldehydes under visible light can be achieved on BiVO4 crystals with spatial separation of dual-cocatalysts.

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Low-temperature selective aerobic oxidation of cyclohexanol to cyclohexanone over n-type metal oxide-supported Au nanoparticles

Catalysis Communications ◽

10.1016/j.catcom.2020.106089 ◽

2020 ◽

Vol 144 ◽

pp. 106089

Author(s):

Tadahiro Niwa ◽

Shin-ichi Naya ◽

Hiroaki Tada

Keyword(s):

Low Temperature ◽

Metal Oxide ◽

Au Nanoparticles ◽

Aerobic Oxidation ◽

Selective Aerobic Oxidation

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Self-Exfoliated Synthesis of Transition Metal Phosphate Nanolayers for Selective Aerobic Oxidation of Ethyl Lactate to Ethyl Pyruvate

ACS Catalysis ◽

10.1021/acscatal.9b04452 ◽

2020 ◽

Vol 10 (7) ◽

pp. 3958-3967

Author(s):

Wei Zhang ◽

Paula Oulego ◽

Sandeep K. Sharma ◽

Xiu-Lin Yang ◽

Lain-Jong Li ◽

...

Keyword(s):

Transition Metal ◽

Ethyl Pyruvate ◽

Aerobic Oxidation ◽

Ethyl Lactate ◽

Metal Phosphate ◽

Selective Aerobic Oxidation

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On the selective aerobic oxidation of benzyl alcohol with Pd/Au-nanoparticles in batch and flow

Nanotechnology Reviews ◽

10.1515/ntrev-2012-0085 ◽

2014 ◽

Vol 3 (1) ◽

pp. 99-110 ◽

Cited By ~ 2

Author(s):

Hannes Alex ◽

Norbert Steinfeldt ◽

Klaus Jähnisch ◽

Matthias Bauer ◽

Sandra Hübner

Keyword(s):

Catalytic Activity ◽

Benzyl Alcohol ◽

Aerobic Oxidation ◽

X Ray ◽

X Ray Scattering ◽

Oxidation Of Benzyl Alcohol ◽

Transmission Electron ◽

Vis Spectroscopy ◽

Selective Aerobic Oxidation

AbstractNanoparticles (NP) have specific catalytic properties, which are influenced by parameters like their size, shape, or composition. Bimetallic NPs, composed of two metal elements can show an improved catalytic activity compared to the monometallic NPs. We, herein, report on the selective aerobic oxidation of benzyl alcohol catalyzed by unsupported Pd/Au and Pd NPs at atmospheric pressure. NPs of varying compositions were synthesized and characterized by UV/Vis spectroscopy, transmission electron microscopy (TEM), and small-angle X-ray scattering (SAXS). The NPs were tested in the model reaction regarding their catalytic activity, stability, and recyclability in batch and continuous procedure. Additionally, in situ extended X-ray absorption fine structure (EXAFS) measurements were performed in order to get insight in the process during NP catalysis.

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