Structural Elucidation, Aggregation, and Dynamic Behaviour of
N,N,N,N
‐Copper(I) Schiff Base Complexes in Solid and in Solution: A Combined NMR, X‐ray Spectroscopic and Crystallographic Investigation
Two mononuclear iron(III) complexes, [FeL1Cl]∙CH3CN (1) and [FeL2(N3)] (2) {H2L1= N,N′-bis(5-chlorosalicylidene)diethylenetriamine and H2L2= N,N′-bis(5-bromosalicylidene)diethylenetriamine}, have been synthesized and characterized by X-ray crystallographic studies. In the solid state, there are strong...
Ninety Cr(III) macrocyclic Schiff base complexes of the type [CrL_n^(1-10) X_2 ]X(Where X = Cl- or NO-3 or CH3COO- and = macrocyclic Schiff base ligands derived from condensation of trimesic acid or p-phthalic acid or squaric acid with different aliphatic diamines) have been synthesised and characterised by elemental analysis; molar conductance; electronic spectra; IR; magnetic moment and XPS i.e. X-ray Photoelectron spectra data. An octahedral geometry was established for them.
A pair of tetranuclear chiral Cu(ii)-Schiff-base complexes were synthesized using enantiomerically pure (S)-H2L and (R)-H2L ligands. These were characterised using single-crystal X-ray diffraction and CD spectroscopy and their biological activity tested.