Determination of CMC from Liquid Junction Potential Measurements

1972 ◽  
Vol 61 (4) ◽  
pp. 639-641 ◽  
Author(s):  
Edward J. Williams ◽  
Victor F. Smolen
1992 ◽  
Vol 21 (8) ◽  
pp. 1619-1622 ◽  
Author(s):  
Akira Yamauchi ◽  
Minako Inoue

Electrochem ◽  
2021 ◽  
Vol 2 (2) ◽  
pp. 197-215
Author(s):  
Jerzy J. Jasielec

This work is aimed to give an electrochemical insight into the ionic transport phenomena in the cellular environment of organized brain tissue. The Nernst–Planck–Poisson (NPP) model is presented, and its applications in the description of electrodiffusion phenomena relevant in nanoscale neurophysiology are reviewed. These phenomena include: the signal propagation in neurons, the liquid junction potential in extracellular space, electrochemical transport in ion channels, the electrical potential distortions invisible to patch-clamp technique, and calcium transport through mitochondrial membrane. The limitations, as well as the extensions of the NPP model that allow us to overcome these limitations, are also discussed.


2018 ◽  
Vol 35 (2) ◽  
pp. 79
Author(s):  
Bernadete F. Cavalcanti ◽  
Lourdes Cristina Lucena Agostinho ◽  
Luciano Nascimento

Measurements of parameters expressed in terms of carbonic species such as Alkalinity and Acidity of saline waters do not analyze the influence of external parameters to the titration such as Total free and associated Carbonic Species Concentration, activity coefficient, ion pairing formation and Residual Liquid Junction Potential in pH measurements. This paper shows the development of F5BC titration function based on the titrations developed by Gran (1952) for the carbonate system of natural waters. For practical use, samples of saline watersfrom Pocinhos reservoir in Paraiba were submitted to titration and linear regression analysis. Results showed that F5BC involves F1x and F2x Gran functions determination, respectively, for Alkalinity and Acidity calculations without knowing “a priori” the endpoint of the titration. F5BC also allows the determination of the First and Second Apparent Dissociation Constant of the carbonate system of saline and high ionic strength waters.


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