Temperature-dependent rate coefficients and mechanism for the gas-phase reaction of chlorine atoms with acetone

2010 ◽  
Vol 42 (12) ◽  
pp. 724-734 ◽  
Author(s):  
Manolis N. Romanias ◽  
Vassileios G. Stefanopoulos ◽  
Dimitrios K. Papanastasiou ◽  
Vassileios C. Papadimitriou ◽  
Panos Papagiannakopoulos
Keyword(s):  
Gas Phase ◽  
Rate Coefficients ◽  
Phase Reaction ◽  
Temperature Dependent ◽  
Chlorine Atoms ◽  
Gas Phase Reaction ◽  
Dependent Rate

Temperature Dependent Rate Coefficients for the Gas-Phase Reaction of the OH Radical with Linear (L2, L3) and Cyclic (D3, D4) Permethylsiloxanes

2018 ◽  
Vol 122 (17) ◽  
pp. 4252-4264 ◽  
Author(s):  
François Bernard ◽  
Dimitrios K. Papanastasiou ◽  
Vassileios C. Papadimitriou ◽  
James B. Burkholder
Keyword(s):  
Gas Phase ◽  
Rate Coefficients ◽  
Phase Reaction ◽  
Oh Radical ◽  
Temperature Dependent ◽  
Gas Phase Reaction ◽  
Dependent Rate

Rate Coefficients for the Gas-Phase Reaction of Chlorine Atoms with a Series of Methoxylated Aromatic Compounds

2014 ◽  
Vol 118 (10) ◽  
pp. 1777-1784 ◽  
Author(s):  
Amélie Lauraguais ◽  
Iustinian Bejan ◽  
Ian Barnes ◽  
Peter Wiesen ◽  
Cécile Coeur-Tourneur ◽  
...  
Keyword(s):  
Gas Phase ◽  
Aromatic Compounds ◽  
Rate Coefficients ◽  
Phase Reaction ◽  
Chlorine Atoms ◽  
Gas Phase Reaction ◽  
Methoxylated Aromatic

Temperature Dependent Rate Constants for the Gas-Phase Reaction between OH and CH3OCl

1996 ◽  
Vol 100 (9) ◽  
pp. 3601-3606 ◽  
Author(s):  
John N. Crowley ◽  
Pedro Campuzano-Jost ◽  
Geert K. Moortgat
Keyword(s):  
Gas Phase ◽  
Rate Constants ◽  
Phase Reaction ◽  
Temperature Dependent ◽  
Gas Phase Reaction ◽  
Dependent Rate

scholarly journals Temperature dependent kinetics of the gas-phase reaction of OH radicals with EMS

2011 ◽  
Vol 56 (4-5) ◽  
pp. 391-396
Author(s):  
Kun Wang ◽  
MaoFa Ge ◽  
WeiGang Wang
Keyword(s):  
Gas Phase ◽  
Oh Radicals ◽  
Phase Reaction ◽  
Temperature Dependent ◽  
Gas Phase Reaction ◽  
Kinetics Of

scholarly journals Reactive quenching of electronically excited NO<sub>2</sub><sup>∗</sup> and NO<sub>3</sub><sup>∗</sup> by H<sub>2</sub>O as potential sources of atmospheric HO<sub><i>x</i></sub> radicals

2018 ◽  
Vol 18 (19) ◽  
pp. 14005-14015 ◽  
Author(s):  
Terry J. Dillon ◽  
John N. Crowley
Keyword(s):  
Gas Phase ◽  
Laser Excitation ◽  
Pulsed Laser ◽  
Work Rate ◽  
Rate Coefficients ◽  
Phase Reaction ◽  
Gas Phase Reaction ◽  
Upper Limit ◽  
Upper Limits ◽  
Electronically Excited

Abstract. Pulsed laser excitation of NO2 (532–647 nm) or NO3 (623–662 nm) in the presence of H2O was used to initiate the gas-phase reaction NO2∗+H2O → products (Reaction R5) and NO3∗+H2O → products (Reaction R12). No evidence for OH production in Reactions (R5) or (R12) was observed and upper limits for OH production of k5b/k5<1×10-5 and k12b/k12<0.03 were assigned. The upper limit for k5b∕k5 renders this reaction insignificant as a source of OH in the atmosphere and extends the studies (Crowley and Carl, 1997; Carr et al., 2009; Amedro et al., 2011) which demonstrate that the previously reported large OH yield by Li et al. (2008) was erroneous. The upper limit obtained for k12b∕k12 indicates that non-reactive energy transfer is the dominant mechanism for Reaction (R12), though generation of small but significant amounts of atmospheric HOx and HONO cannot be ruled out. In the course of this work, rate coefficients for overall removal of NO3∗ by N2 (Reaction R10) and by H2O (Reaction R12) were determined: k10=(2.1±0.1)×10-11 cm3 molecule−1 s−1 and k12=(1.6±0.3)×10-10 cm3 molecule−1 s−1. Our value of k12 is more than a factor of 4 smaller than the single previously reported value.

Kinetics of the gas phase reaction of chlorine atoms with a series of alkenes, alkynes and aromatic species at 295 K

1988 ◽  
Vol 45 (2) ◽  
pp. 167-175 ◽  
Author(s):  
Timothy J. Wallington ◽  
Loretta M. Skewes ◽  
Walter O. Siegl
Keyword(s):  
Gas Phase ◽  
Phase Reaction ◽  
Chlorine Atoms ◽  
Gas Phase Reaction ◽  
Aromatic Species ◽  
Kinetics Of

Gas-phase ozonolysis of β-ocimene: Temperature dependent rate coefficients and product distribution

2016 ◽  
Vol 147 ◽  
pp. 46-54 ◽  
Author(s):  
Elizabeth Gaona-Colmán ◽  
María B. Blanco ◽  
Ian Barnes ◽  
Mariano A. Teruel
Keyword(s):  
Gas Phase ◽  
Product Distribution ◽  
Rate Coefficients ◽  
Temperature Dependent ◽  
Dependent Rate

Temperature‐dependent rate coefficients for the gas‐phase OH + furan‐2,5‐dione (C 4 H 2 O 3 , maleic anhydride) reaction

2020 ◽  
Vol 52 (10) ◽  
pp. 623-631 ◽  
Author(s):  
Aparajeo Chattopadhyay ◽  
Vassileios C. Papadimitriou ◽  
Paul Marshall ◽  
James B. Burkholder
Keyword(s):  
Maleic Anhydride ◽  
Gas Phase ◽  
Rate Coefficients ◽  
Temperature Dependent ◽  
Dependent Rate

Rate coefficients for the gas-phase reaction of OH radicals with selected dihydroxybenzenes and benzoquinones

2000 ◽  
Vol 32 (11) ◽  
pp. 696-702 ◽  
Author(s):  
R. I. Olariu ◽  
I. Barnes ◽  
K. H. Becker ◽  
B. Klotz
Keyword(s):  
Gas Phase ◽  
Rate Coefficients ◽  
Oh Radicals ◽  
Phase Reaction ◽  
Gas Phase Reaction
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