Mathematical modeling of binary compounds with the presence of a phase transition layer

Author(s):  
Irina G. Nizovtseva ◽  
Ilya O. Starodumov ◽  
Eugeny V. Pavlyuk ◽  
Alexander A. Ivanov
Author(s):  
Liubov Toropova ◽  
Danil Aseev ◽  
Sergei Osipov ◽  
Alexander Ivanov

This paper is devoted to the mathematical modeling of a combined effect of directional and bulk crystallization in a phase transition layer with allowance for nucleation and evolution of newly born particles. We consider two models with and without fluctuations in crystal growth velocities, which are analytically solved using the saddle-point technique. The particle-size distribution function, solid-phase fraction in a supercooled two-phase layer, its thickness and permeability, solidification velocity, and desupercooling kinetics are defined. This solution enables us to characterize the mushy layer composition. We show that the region adjacent to the liquid phase is almost free of crystals and has a constant temperature gradient. Crystals undergo intense growth leading to fast mushy layer desupercooling in the middle of a two-phase region. The mushy region adjacent to the solid material is filled with the growing solid phase structures and is almost desupercooled.


2020 ◽  
Vol 532 ◽  
pp. 125420
Author(s):  
D.V. Alexandrov ◽  
A.A. Ivanov ◽  
I.V. Alexandrova

Analysis ◽  
2008 ◽  
Vol 28 (1) ◽  
Author(s):  
Thomas Blesgen

This article studies diffusion in solids in the case of two phases under isothermal conditions where due to plastic effects the number of vacancies changes when crossing a transition layer, i.e. a reconstitutive phase transition. A segregation model is derived and the equations are studied in the limit of a sharp interface. A Gibbs–Thomson law is derived and it is shown that the vacancy component of the chemical potential jumps across the transition layer thereby explaining recent experimental observations. The thermodynamic correctness of the model is shown as well as the existence of weak solutions with logarithmic free energies.


2021 ◽  
Vol 8 (4) ◽  
pp. 830-841
Author(s):  
Ya. I. Sokolovskyy ◽  
◽  
I. B. Boretska ◽  
B. I. Gayvas ◽  
I. M. Kroshnyy ◽  
...  

The article deals with constructing and implementing mathematical models of non-isothermal moisture transfer during drying of anisotropic capillary-porous materials, in particular wood, taking into account the movement of the evaporation zone for non-steady drying schedules, as well as to the development of effective analytical and numerical methods for their implementation. An analytical-numerical method for the determination of non-isothermal moisture transfer under non-steady schedules of the drying process has been developed, taking into account the dynamics of the phase transition boundary change. Calculation relationships are established for determining the phase transition temperature taking into account transport gradients and time for which the relative saturation reaches the boundaries of the phase transition.


2014 ◽  
Vol 19 (7) ◽  
pp. 1889-1909 ◽  
Author(s):  
Alessia Berti ◽  
◽  
Claudio Giorgi ◽  
Angelo Morro ◽  
◽  
...  

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