Studies on Alternating Copolymerization of Ethylene and Carbon monoxide using Nickel‐Based Catalyst: Co‐Catalyst and the Polarity of Solvent

2021 ◽  
pp. 2100047
Author(s):  
Zhengwei Bie ◽  
Bo‐Geng Li ◽  
Jijiang Hu ◽  
Zhen Yao
Author(s):  
Markus Allmendinger ◽  
Robert Eberhardt ◽  
Gerrit A. Luinstra ◽  
Ferenc Molnar ◽  
Bernhard Rieger

1997 ◽  
Vol 119 (52) ◽  
pp. 12779-12795 ◽  
Author(s):  
Kyoko Nozaki ◽  
Naomasa Sato ◽  
Yoichi Tonomura ◽  
Masako Yasutomi ◽  
Hidemasa Takaya ◽  
...  

2002 ◽  
Vol 124 (20) ◽  
pp. 5646-5647 ◽  
Author(s):  
Markus Allmendinger ◽  
Robert Eberhardt ◽  
Gerrit Luinstra ◽  
Bernhard Rieger

2001 ◽  
Vol 79 (5-6) ◽  
pp. 587-592 ◽  
Author(s):  
Christophe Moineau ◽  
Giuseppe Mele ◽  
Howard Alper

The copolymerization of carbon monoxide with different olefins bearing carbamate and amide functionalities was effected using [Pd(CH3CN)4](BF4)2 as the catalyst and (R,R)-Me-DUPHOS (2:1 (v/v) MeNO2–MeOH or CH2Cl2 as the solvent). The products constitute a new class of functionalized copolymers, and were found to be optically active with a mixture of 1,4-ketone and spiroketal repeating units in the backbone. The influence of different parameters on the copolymerization of methyl N-(3-butenyl)carbamate with carbon monoxide was examined.Key words: copolymerization, carbon monoxide, olefins bearing carbamate and amide functionalities.


2001 ◽  
Vol 123 (4) ◽  
pp. 534-544 ◽  
Author(s):  
Kyoko Nozaki ◽  
Hatsumi Komaki ◽  
Yasutoyo Kawashima ◽  
Tamejiro Hiyama ◽  
Toshiaki Matsubara

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