Oligomerization and polymerization of 5-ethylidene-2-norbornene by cationic palladium and nickel catalysts

Nickel- and palladium-based catalyst systems were developed to convert 5-ethylidene-2-norbornene (ENB) to oligomers and polymers with highly controllable molecular weights.

Formation of Acetals and Ketals from Carbonyl Compounds: A New and Highly Efficient Method Inspired by Cationic Palladium

The development of a new, highly efficient, and simple method for masking carbonyl groups as acetals and ketals is described. This methodology relies on the nature of the palladium catalyst to direct the acetalization/ketalization reaction. This new protocol is mild and proceed with a very low catalyst loading at ambient temperatures. The method has been extended to a wide variety of different carbonyl compounds with various steric encumbrances to form the corresponding acetals and ketals in excellent yields.