Synthesis of novel high oil-absorption resins of poly(methyl methacrylate-butyl methacrylate) by surface-initiated atom transfer radical polymerization using activators regenerated by electron transfer for efficient removal of oil

2012 ◽  
Vol 61 (12) ◽  
pp. 1786-1791 ◽  
Author(s):  
Naiyi Ji ◽  
Hou Chen ◽  
Guangxi Zong ◽  
Dongju Wang
Keyword(s):  
Electron Transfer ◽  
Methyl Methacrylate ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Butyl Methacrylate ◽  
Atom Transfer ◽  
Oil Absorption ◽  
Efficient Removal ◽  
Poly Methyl Methacrylate

scholarly journals Synthesis of Poly(methyl methacrylate)-b-poly(N-isopropylacrylamide) Block Copolymer by Redox Polymerization and Atom Transfer Radical Polymerization

2018 ◽  
Vol 18 (3) ◽  
pp. 537 ◽  
Author(s):  
Melahat Göktaş ◽  
Guodong Deng
Keyword(s):  
Block Copolymers ◽  
Methyl Methacrylate ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Gel Permeation Chromatography ◽  
High Yield ◽  
Resonance Spectroscopy ◽  
Atom Transfer ◽  
Poly Methyl Methacrylate ◽  
Redox Polymerization

Poly(methyl methacrylate)-b-poly(N-isopropylacrylamide) [PMMA-b-PNIPAM] block copolymers were obtained by a combination of redox polymerization and atom transfer radical polymerization (ATRP) methods in two steps. For this purpose, PMMA macroinitator (ATRP-macroinitiator) was synthesized by redox polymerization of methyl methacrylate and 3-bromo-1-propanol using Ce(NH4)2(NO3)6 as a catalyst. The synthesis of PMMA-b-PNIPAM block copolymers was carried out by means of ATRP of ATRP-macroinitiator and NIPAM at 60 °C. The block copolymers were obtained in high yield and high molecular weight. The characterization of products was accomplished by using multi instruments and methods such as nuclear magnetic resonance spectroscopy, Fourier transform infrared spectroscopy, gel permeation chromatography, and thermogravimetric analysis.

Well-defined poly(methyl methacrylate) grafted to polyethylene with reverse atom transfer radical polymerization initiated by peroxides

Polymer ◽  
2003 ◽  
Vol 44 (25) ◽  
pp. 7661-7669 ◽  
Author(s):  
Katsuhiro Yamamoto ◽  
Hiroyuki Tanaka ◽  
Masato Sakaguchi ◽  
Shigetaka Shimada
Keyword(s):  
Methyl Methacrylate ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Atom Transfer ◽  
Poly Methyl Methacrylate

Controlled synthesis of poly[(butyl methacrylate)-co -(butyl acrylate)] via activator regenerated by electron transfer atom transfer radical polymerization: insights and improvement

2014 ◽  
Vol 63 (5) ◽  
pp. 848-857 ◽  
Author(s):  
Kevin A Payne ◽  
Paul HM Van Steenberge ◽  
Dagmar R D'hooge ◽  
Marie-Françoise Reyniers ◽  
Guy B Marin ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Butyl Acrylate ◽  
Butyl Methacrylate ◽  
Controlled Synthesis ◽  
Atom Transfer
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