Controlled synthesis of poly[(butyl methacrylate)-co -(butyl acrylate)] via activator regenerated by electron transfer atom transfer radical polymerization: insights and improvement

2014 ◽  
Vol 63 (5) ◽  
pp. 848-857 ◽  
Author(s):  
Kevin A Payne ◽  
Paul HM Van Steenberge ◽  
Dagmar R D'hooge ◽  
Marie-Françoise Reyniers ◽  
Guy B Marin ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Butyl Acrylate ◽  
Butyl Methacrylate ◽  
Controlled Synthesis ◽  
Atom Transfer

scholarly journals Modelling and experimental investigation of ARGET/AGET atom transfer radical polymerization systems

2021 ◽  
Author(s):  
Ethan Massicotte
Keyword(s):  
Experimental Investigation ◽  
Electron Transfer ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Monte Carlo Model ◽  
Point Of View ◽  
Butyl Methacrylate ◽  
Atom Transfer ◽  
Aget Atrp ◽  
Dispersed System

Activators Generated by Electron Transfer (AGET) and Activators Regenerated by Electron Transfer (ARGET) Atom Transfer Radical Polymerization (ATRP) are emerging topics within the polymerization field. These techniques allow for better control over polymer structure and polymer size distributions than conventional polymerizations. However, investigations into these processes are lacking, especially from a modelling point of view. Therefore, a kinetic model of the ARGET ATRP of butyl methacrylate (BMA) in a solution medium and Hybrid Monte Carlo model of the AGET ATRP of butyl acrylate (BA) in a dispersed system were developed and compared with data. In addition, an experimental investigation of the AGET ATRP of BA was carried out to study the kinetic aspects of this polymerization. The results of these studies demonstrate that both models have relatively strong predictive powers, and that different kinetic regimes appear to be available within the dispersed system studied experientially.

scholarly journals Modelling and experimental investigation of ARGET/AGET atom transfer radical polymerization systems

2021 ◽  
Author(s):  
Ethan Massicotte
Keyword(s):  
Experimental Investigation ◽  
Electron Transfer ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Monte Carlo Model ◽  
Point Of View ◽  
Butyl Methacrylate ◽  
Atom Transfer ◽  
Aget Atrp ◽  
Dispersed System

Activators Generated by Electron Transfer (AGET) and Activators Regenerated by Electron Transfer (ARGET) Atom Transfer Radical Polymerization (ATRP) are emerging topics within the polymerization field. These techniques allow for better control over polymer structure and polymer size distributions than conventional polymerizations. However, investigations into these processes are lacking, especially from a modelling point of view. Therefore, a kinetic model of the ARGET ATRP of butyl methacrylate (BMA) in a solution medium and Hybrid Monte Carlo model of the AGET ATRP of butyl acrylate (BA) in a dispersed system were developed and compared with data. In addition, an experimental investigation of the AGET ATRP of BA was carried out to study the kinetic aspects of this polymerization. The results of these studies demonstrate that both models have relatively strong predictive powers, and that different kinetic regimes appear to be available within the dispersed system studied experientially.

scholarly journals A Cu(ii) metal–organic framework as a recyclable catalyst for ARGET ATRP

2016 ◽  
Vol 7 (47) ◽  
pp. 7199-7203 ◽  
Author(s):  
Hui-Chun Lee ◽  
Markus Antonietti ◽  
Bernhard V. K. J. Schmidt
Keyword(s):  
Electron Transfer ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Metal Organic Framework ◽  
Recyclable Catalyst ◽  
Atom Transfer ◽  
Arget Atrp ◽  
Metal Organic ◽  
Organic Framework

A Cu(ii) MOF can serve as an comprehensive catalyst for activators regenerated by electron transfer atom transfer radical polymerization (ARGET ATRP) in the synthesis of benzyl methacrylate, styrene, isoprene and 4-vinylpyridine.

Atom Transfer Radical Polymerization of iso-Butyl Methacrylate in Microemulsion with Cationic and Non-Ionic Emulsifiers

2008 ◽  
Vol 29 (3) ◽  
pp. 264-264
Author(s):  
Yasuyuki Kagawa ◽  
Masahiro Kawasaki ◽  
Per B. Zetterlund ◽  
Hideto Minami ◽  
Masayoshi Okubo
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Butyl Methacrylate ◽  
Atom Transfer
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