scholarly journals Approaching New Biomaterials: Copolymerization Characteristics of Vinyl esters with Norbornenes, Allyl esters and Allyl ethers

2021 ◽  
Author(s):  
Patrick Steinbauer ◽  
Robert Liska ◽  
Stefan Baudis
Keyword(s):  
Vinyl Esters ◽  
Allyl Ethers ◽  
Allyl Esters

scholarly journals Transition-metal-free allylation of 2-azaallyls with allyl ethers through polar and radical mechanisms

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Guogang Deng ◽  
Shengzu Duan ◽  
Jing Wang ◽  
Zhuo Chen ◽  
Tongqi Liu ◽  
...  
Keyword(s):  
Transition Metal ◽  
Allyl Ether ◽  
Metal Catalyst ◽  
Metal Free ◽  
Allyl Ethers ◽  
Bond Forming ◽  
Allyl Halides ◽  
Synthetic Utility ◽  
Insight Into ◽  
Allyl Esters

AbstractAllylation of nucleophiles with highly reactive electrophiles like allyl halides can be conducted without metal catalysts. Less reactive electrophiles, such as allyl esters and carbonates, usually require a transition metal catalyst to facilitate the allylation. Herein, we report a unique transition-metal-free allylation strategy with allyl ether electrophiles. Reaction of a host of allyl ethers with 2-azaallyl anions delivers valuable homoallylic amine derivatives (up to 92%), which are significant in the pharmaceutical industry. Interestingly, no deprotonative isomerization or cyclization of the products were observed. The potential synthetic utility and ease of operation is demonstrated by a gram scale telescoped preparation of a homoallylic amine. In addition, mechanistic studies provide insight into these C(sp3)–C(sp3) bond-forming reactions.

Catalytic Activity of Rhodium-Siloxide Complexes in Hydrosilylation of Allyl Ethers and Allyl Esters

2008 ◽  
pp. 415-419
Author(s):  
Bogdan Marciniec ◽  
Edyta Walczuk ◽  
Paulina Baejewska-Chadyniak ◽  
Dariusz Chadyniak ◽  
Magorzata Kujawa-Welten ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Allyl Ethers ◽  
Allyl Esters

Catalytic Activity of Rhodium-Siloxide Complexes in Hydrosilylation of Allyl Ethers and Allyl Esters

2008 ◽  
pp. 415-419 ◽  
Author(s):  
Bogdan Marciniec ◽  
Edyta Walczuk ◽  
Paulina Baejewska-Chadyniak ◽  
Dariusz Chadyniak ◽  
Magorzata Kujawa-Welten ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Allyl Ethers ◽  
Allyl Esters

Catalytic Activity of Rhodium-Siloxide Complexes in Hydrosilylation of Allyl Ethers and Allyl Esters

ChemInform ◽  
2005 ◽  
Vol 36 (20) ◽  
Author(s):  
Bogdan Marciniec ◽  
Edyta Walczuk ◽  
Paulina Blazejewska-Chadyniak ◽  
Dariusz Chadyniak ◽  
Malgorzata Kujawa-Welten ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Allyl Ethers ◽  
Allyl Esters

scholarly journals Synthesis of 5,6,7,8-Tetrahydroquinolines by Thermolysis of Oxime O-Allyl Ethers in the Presence of Boron Trifluoride Etherate.

1993 ◽  
Vol 41 (7) ◽  
pp. 1297-1298 ◽  
Author(s):  
Junko KOYAMA ◽  
Tamaki OGURA ◽  
Kiyoshi TAGAHARA ◽  
Masaaki MIYASHITA ◽  
Hiroshi IRIE
Keyword(s):  
Boron Trifluoride ◽  
Boron Trifluoride Etherate ◽  
Allyl Ethers

Enantioselective Allylations of Azlactones with Unsymmetrical Acyclic Allyl Esters

1999 ◽  
Vol 121 (46) ◽  
pp. 10727-10737 ◽  
Author(s):  
Barry M. Trost ◽  
Xavier Ariza
Keyword(s):  
Allyl Esters
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