Synthesis and characterization of polyurethane ionomers with trimellitic anhydride and dimethylol propionic acid for waterborne self-emulsifying dispersions

2013 ◽  
Vol 52 (5) ◽  
pp. 680-690 ◽  
Author(s):  
Jasmin Bullermann ◽  
Rüdiger Spohnholz ◽  
Stefan Friebel ◽  
Tunga Salthammer
2004 ◽  
Vol 42 (7) ◽  
pp. 1758-1767 ◽  
Author(s):  
Michael Malkoch ◽  
Hans Claesson ◽  
Peter Löwenhielm ◽  
Eva Malmström ◽  
Anders Hult

1997 ◽  
Vol 50 (9) ◽  
pp. 939 ◽  
Author(s):  
Fang Chen ◽  
Parveen Akhtar ◽  
Leon A. P. Kane-Maguire ◽  
Gordon G. Wallace

A range of optically active pyrrole monomers have been synthesized in which a chiral sub- stituent is covalently bonded either to the pyrrole N or C3 ring position, namely (–)-(1R)-4-methyl-N-(1-phenylethyl)pyrrole-3-carboxamide, (+)-(1S)-4-methyl-N-(1-phenylethyl)pyrrole-3-carboxamide, (–)-(1R)-4-methyl-N-(1-naphthylethyl)pyrrole-3-carboxamide, (+)-(1S)-4-methyl-N-(1-naphthylethyl)pyrrole-3-carboxamide, (+)-(2S)-2-(1H-pyrrol-1-yl)propionic acid, (+)-(1S)-N-(1-phenyl-ethyl)pyrrole, and (–)-(1R)-N-(1-phenylethyl)pyrrole. Their chiroptical properties have been established by circular dichroism spectroscopy. Electropolymerization of the three N-substituted pyrrole monomers provided films of chiral conducting polymers, whose electrical and spectroscopic properties are described. Although oxidation of the C3 substituted pyrrole monomers was also facile, electrodeposition was poor and films of the associated polymers could not be obtained.


Sign in / Sign up

Export Citation Format

Share Document