A Theoretical Study on Non‐Bridging Dimer Formation of a Cationic Platinum Complex with a Redox‐Active Ligand

A new inorganic molecule [ Co(Hbim) ( C 6 H 4 O 2)( NH 3)2]2 that can be used as a new optically durable molecular switch was theoretically designed in the framework of density functional theory. Three stable minima, belonging to 1 A g , 5 A 1, and 9 A g states, were found in the complex. Theoretically predicted infrared spectra of the complexes showed that a strong peak of NH stretching vibration is observed at 2690, 2120, and 2770 cm -1 in the 1 A g , 5 A 1, and 9 A g states, respectively. The apparent red shift of the NH stretching vibration band in the 5 A 1 state make it possible to distinguish the electronic state from others (1 A g and 9 A g ). This means that the complex can be used as a molecular level switch whose memory can be stably read by IR light without any photoreaction process; namely, without memory degradation.

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Isolation of a uranium(iii) benzophenone ketyl radical that displays redox-active ligand behaviour

Dalton Transactions ◽

10.1039/c4dt01636j ◽

2014 ◽

Vol 43 (48) ◽

pp. 17885-17888 ◽

Cited By ~ 20

Author(s):

Ellen M. Matson ◽

John J. Kiernicki ◽

Nickolas H. Anderson ◽

Phillip E. Fanwick ◽

Suzanne C. Bart

Keyword(s):

Ketyl Radical ◽

Radical Complex ◽

Redox Active Ligand ◽

Active Ligand ◽

Redox Active ◽

Reducing Equivalents

The first uranium(iii) charge separated ketyl radical complex, Tp*2U(OC·Ph2), has been isolated and acts as a potent two-electron reductant with reducing equivalents derived from both uranium and the redox-active benzophenone.

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Metal–Organic Frameworks Derived from Calcium and Strontium Complexes of a Redox-Active Ligand

Inorganic Chemistry ◽

10.1021/acs.inorgchem.0c03647 ◽

2021 ◽

Vol 60 (5) ◽

pp. 3238-3248

Author(s):

Natalia L. Bazyakina ◽

Valentin M. Makarov ◽

Sergey Yu. Ketkov ◽

Artem S. Bogomyakov ◽

Roman V. Rumyantcev ◽

...

Keyword(s):

Metal Organic Frameworks ◽

Redox Active Ligand ◽

Active Ligand ◽

Redox Active ◽

Metal Organic

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Catalytic nitrene transfer by a zirconium(iv) redox-active ligand complex

Chemical Science ◽

10.1039/c0sc00414f ◽

2011 ◽

Vol 2 (1) ◽

pp. 166-169 ◽

Cited By ~ 117

Author(s):

Andy I. Nguyen ◽

Ryan A. Zarkesh ◽

David C. Lacy ◽

Megan K. Thorson ◽

Alan F. Heyduk

Keyword(s):

Ligand Complex ◽

Nitrene Transfer ◽

Redox Active Ligand ◽

Active Ligand ◽

Redox Active

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Synthesis and properties of a redox active ligand with bispicorylamino groups and its dinuclear complex

Polyhedron ◽

10.1016/j.poly.2006.10.031 ◽

2007 ◽

Vol 26 (9-11) ◽

pp. 2174-2178 ◽

Cited By ~ 5

Author(s):

Masafumi Yano ◽

Masayuki Fujita ◽

Masaya Miyake ◽

Masakazu Tatsumi ◽

Tatsuo Yajima ◽

...

Keyword(s):

Dinuclear Complex ◽

Redox Active Ligand ◽

Active Ligand ◽

Redox Active

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Steric and Electronic Consequences of Flexibility in a Tetradentate Redox-Active Ligand: Ti(IV) and Zr(IV) Complexes

Inorganic Chemistry ◽

10.1021/ic101468p ◽

2011 ◽

Vol 50 (1) ◽

pp. 125-135 ◽

Cited By ~ 18

Author(s):

Géza Szigethy ◽

Alan F. Heyduk

Keyword(s):

Redox Active Ligand ◽

Active Ligand ◽

Redox Active

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Correction: Redox-active ligand based Mn(i)-catalyst for hydrosilylative ester reduction

Chemical Communications ◽

10.1039/d1cc90429a ◽

2022 ◽

Author(s):

Soumi Chakraborty ◽

Arpan Das ◽

Swadhin K. Mandal

Keyword(s):

Redox Active Ligand ◽

Active Ligand ◽

Redox Active

Correction for ‘Redox-active ligand based Mn(i)-catalyst for hydrosilylative ester reduction’ by Soumi Chakraborty et al., Chem. Commun., 2021, 57, 12671–12674, DOI: 10.1039/D1CC05614J.

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