The Rotational Spectrum of CHF3 in the Submillimeter-Wave and Far-Infrared Region: Observation of the K = 3 Line Splitting

1994 ◽  
Vol 163 (2) ◽  
pp. 521-528 ◽  
Author(s):  
G. Cazzoli ◽  
L. Cludi ◽  
G. Cotti ◽  
L. Dore ◽  
C.D. Esposti ◽  
...  
1990 ◽  
Vol 45 (6) ◽  
pp. 837-838 ◽  
Author(s):  
Koichi M. T. Yamada

AbstractThe pure rotational spectrum of NNO has been observed as an impurity in the NO spectrum which has been recorded with a high resolution Fourier transform spectrometer. The observed high-J transitions in the ground vibrational state were analyzed by a least-squares fit together with the available millimeter and submillimeter wave data. It has been proved that the highly precise data of Maki et al. [3] can be used as a wavenumber standard for the far infrared.


2000 ◽  
Vol 55 (5) ◽  
pp. 486-490 ◽  
Author(s):  
Holger S. P. Müller ◽  
Ralf Gendriesch ◽  
Frank Lewen ◽  
Gisbert Winnewisser

Abstract The ground state rotational spectrum of H2C18O has been studied between 485 and 835 GHz with a sample of natural isotopic composition. Additional lines have been recorded around 130 GHz and near 1.85 THz, using a recently developed far-infrared laser-sideband spectrometer. The accurate new line frequencies were fit together with previously published data to obtain greatly improved spectroscopic constants. Both Watson's S and A reduced Hamiltonians have been employed yielding the rotational constants AA = 281 961.215 (82), BA = 36 902.275 51 (36), CA = 32 513.405 89 (36), AA = 281 961.371 (82), BA = 36 904.173 32 (91), and CA = 32 511.524 65 (86) MHz, respectively.


2019 ◽  
Vol 629 ◽  
pp. A112 ◽  
Author(s):  
B. M. Giuliano ◽  
A. A. Gavdush ◽  
B. Müller ◽  
K. I. Zaytsev ◽  
T. Grassi ◽  
...  

Context. Reliable, directly measured optical properties of astrophysical ice analogues in the infrared and terahertz (THz) range are missing from the literature. These parameters are of great importance to model the dust continuum radiative transfer in dense and cold regions, where thick ice mantles are present, and are necessary for the interpretation of future observations planned in the far-infrared region. Aims. Coherent THz radiation allows for direct measurement of the complex dielectric function (refractive index) of astrophysically relevant ice species in the THz range. Methods. We recorded the time-domain waveforms and the frequency-domain spectra of reference samples of CO ice, deposited at a temperature of 28.5 K and annealed to 33 K at different thicknesses. We developed a new algorithm to reconstruct the real and imaginary parts of the refractive index from the time-domain THz data. Results. The complex refractive index in the wavelength range 1 mm–150 μm (0.3–2.0 THz) was determined for the studied ice samples, and this index was compared with available data found in the literature. Conclusions. The developed algorithm of reconstructing the real and imaginary parts of the refractive index from the time-domain THz data enables us, for the first time, to determine the optical properties of astrophysical ice analogues without using the Kramers–Kronig relations. The obtained data provide a benchmark to interpret the observational data from current ground-based facilities as well as future space telescope missions, and we used these data to estimate the opacities of the dust grains in presence of CO ice mantles.


2010 ◽  
Vol 90 (4) ◽  
pp. 44004 ◽  
Author(s):  
F. E. M. Silveira ◽  
S. M. Kurcbart
Keyword(s):  

2018 ◽  
Vol 10 (6) ◽  
pp. 1-9 ◽  
Author(s):  
Yijun Cai ◽  
Kai Da Xu ◽  
Rongrong Guo ◽  
Jinfeng Zhu ◽  
Qing Huo Liu

1971 ◽  
Vol 31 (6) ◽  
pp. 1837-1837 ◽  
Author(s):  
Mitsukazu Onomichi ◽  
Keiei Kudo ◽  
Toshihiro Arai

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