Pure Rotational Spectrum of H2S in the Far-Infrared Region Measured by FTIR Spectroscopy

1994 ◽  
Vol 166 (2) ◽  
pp. 395-405 ◽  
Author(s):  
K.M.T. Yamada ◽  
S. Klee
1994 ◽  
Vol 163 (2) ◽  
pp. 521-528 ◽  
Author(s):  
G. Cazzoli ◽  
L. Cludi ◽  
G. Cotti ◽  
L. Dore ◽  
C.D. Esposti ◽  
...  

1990 ◽  
Vol 45 (6) ◽  
pp. 837-838 ◽  
Author(s):  
Koichi M. T. Yamada

AbstractThe pure rotational spectrum of NNO has been observed as an impurity in the NO spectrum which has been recorded with a high resolution Fourier transform spectrometer. The observed high-J transitions in the ground vibrational state were analyzed by a least-squares fit together with the available millimeter and submillimeter wave data. It has been proved that the highly precise data of Maki et al. [3] can be used as a wavenumber standard for the far infrared.


2021 ◽  
Vol 23 (14) ◽  
pp. 8549-8556
Author(s):  
Yue Liang ◽  
Yichi Zhang ◽  
Csaba Fábri ◽  
Jiarui Ma ◽  
Jianbao Zhao ◽  
...  

The assignment of the fundamental and the first two hot bands of the –CHO torsional mode in benzaldehyde.


2021 ◽  
Author(s):  
Yue Liang ◽  
Ziqiu Chen ◽  
Brant Billinghurst ◽  
Jianbao Zhao ◽  
Jiarui Ma ◽  
...  

2019 ◽  
Vol 629 ◽  
pp. A112 ◽  
Author(s):  
B. M. Giuliano ◽  
A. A. Gavdush ◽  
B. Müller ◽  
K. I. Zaytsev ◽  
T. Grassi ◽  
...  

Context. Reliable, directly measured optical properties of astrophysical ice analogues in the infrared and terahertz (THz) range are missing from the literature. These parameters are of great importance to model the dust continuum radiative transfer in dense and cold regions, where thick ice mantles are present, and are necessary for the interpretation of future observations planned in the far-infrared region. Aims. Coherent THz radiation allows for direct measurement of the complex dielectric function (refractive index) of astrophysically relevant ice species in the THz range. Methods. We recorded the time-domain waveforms and the frequency-domain spectra of reference samples of CO ice, deposited at a temperature of 28.5 K and annealed to 33 K at different thicknesses. We developed a new algorithm to reconstruct the real and imaginary parts of the refractive index from the time-domain THz data. Results. The complex refractive index in the wavelength range 1 mm–150 μm (0.3–2.0 THz) was determined for the studied ice samples, and this index was compared with available data found in the literature. Conclusions. The developed algorithm of reconstructing the real and imaginary parts of the refractive index from the time-domain THz data enables us, for the first time, to determine the optical properties of astrophysical ice analogues without using the Kramers–Kronig relations. The obtained data provide a benchmark to interpret the observational data from current ground-based facilities as well as future space telescope missions, and we used these data to estimate the opacities of the dust grains in presence of CO ice mantles.


2013 ◽  
Vol 2013 ◽  
pp. 1-8 ◽  
Author(s):  
Emanuele Calabrò ◽  
Salvatore Magazù

FTIR spectroscopy was used to investigate the alterations of the vibration bands in the mid-infrared region of Polyethylene oxide in aqueous solution at 25 mg/mL concentration under exposure up to 4 h to a static magnetic field at 200 mT. FTIR spectroscopic analysis of PEO solution in the range 3500–1000 cm−1 evidenced the stretching vibrations of ether band, C–H symmetric-antisymmetric and bending vibrations of methylene groups, and the C–O–C stretching band. A significant decrease in intensity of symmetric and asymmetric stretching CH2 vibration bands occurred after 2 h and 4 h of exposure, followed by a significant decrease in intensity of scissoring bending in plane CH2 vibration around 1465 cm−1. Finally, the C–O–C stretching band around 1080 cm−1 increased in intensity after 4 h of exposure. This result can be attributed to the increase of formation of the intermolecular hydrogen bonding that occurred in PEO aqueous solution after SMF exposure, due to the reorientation of PEO chain after exposure to SMF. In this scenario, the observed decrease in intensity of CH2 vibration bands can be understood as well considering that the reorientation of PEO chain under the applied SMF induces PEO demicellization.


2010 ◽  
Vol 90 (4) ◽  
pp. 44004 ◽  
Author(s):  
F. E. M. Silveira ◽  
S. M. Kurcbart
Keyword(s):  

2018 ◽  
Vol 10 (6) ◽  
pp. 1-9 ◽  
Author(s):  
Yijun Cai ◽  
Kai Da Xu ◽  
Rongrong Guo ◽  
Jinfeng Zhu ◽  
Qing Huo Liu

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