Activation of Hydrogen on Metal Complexes with Sulfide Ligands and Related Coordination Chemistry of H2S

2002 ◽  
pp. 138-152
Keyword(s):  
Coordination Chemistry ◽  
Metal Complexes ◽  
Sulfide Ligands

Fine-Tuning Electronic Properties of Luminescent Pt(II) Complexes via Vertex-Differentiated Coordination of Sterically Invariant Carborane-Based Ligands

2018 ◽  
Author(s):  
Kent O. Kirlikovali ◽  
Jonathan C. Axtell ◽  
Kierstyn Anderson ◽  
Peter I. Djurovich ◽  
Arnold L. Rheingold ◽  
...  
Keyword(s):  
Coordination Chemistry ◽  
Metal Complexes ◽  
Electronic Properties ◽  
Fine Tuning ◽  
Fine Tune

We report the synthesis of two isomeric Pt(II) complexes ligated by doubly deprotonated 1,1′-bis(<i>o</i>-carborane) (<b>bc</b>). This work provides a potential route to fine-tune the electronic properties of luminescent metal complexes by virtue of vertex-differentiated coordination chemistry of carborane-based ligands.

scholarly journals The coordination chemistry of the neutral tris-2-pyridyl silicon ligand [PhSi(6-Me-2-py)3]

2018 ◽  
Vol 47 (20) ◽  
pp. 7036-7043 ◽  
Author(s):  
Alex J. Plajer ◽  
Annie L. Colebatch ◽  
Markus Enders ◽  
Álvaro García-Romero ◽  
Andrew D. Bond ◽  
...  
Keyword(s):  
Coordination Chemistry ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Pyridyl Ligands

The first transition metal complexes of Si(iv) tris(2-pyridyl) ligands are reported.

scholarly journals A versatile ligand for coordination chemistry: metal complexes of alkyl- or arylsulfonyl amides

1991 ◽  
Vol 181 (2) ◽  
pp. 145-147 ◽  
Author(s):  
Hei-Ying Cheng ◽  
Pai-Hsiu Cheng ◽  
Chor-Fain Lee ◽  
Shie-Ming Peng
Keyword(s):  
Coordination Chemistry ◽  
Metal Complexes

High-spin enforcement in first-row metal complexes of a constrained polyaromatic ligand: synthesis, structure, and properties

2018 ◽  
Vol 42 (23) ◽  
pp. 18667-18677 ◽  
Author(s):  
Lizhu Chen ◽  
Hunter A. Dulaney ◽  
Branford O. Wilkins ◽  
Sarah Farmer ◽  
Yanbing Zhang ◽  
...  
Keyword(s):  
Coordination Chemistry ◽  
Transition Metals ◽  
Metal Complexes ◽  
High Spin ◽  
Structure And Properties ◽  
Polypyridyl Ligand ◽  
Ligand Synthesis

The coordination chemistry of a rigid tetradentate polypyridyl ligand has been developed with first-row transition metals Mn(ii), Fe(ii), Co(ii), Ni(ii), and Zn(ii).

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