CH2ClN Hydrogen cyanide - hydrogen chloride (1/1)

Author(s):  
G. Graner ◽  
E. Hirota ◽  
T. Iijima ◽  
K. Kuchitsu ◽  
D. A. Ramsay ◽  
...  

Author(s):  
E. Hirota ◽  
K. Kuchitsu ◽  
T. Steimle ◽  
J. Vogt ◽  
N. Vogt


Author(s):  
G. Graner ◽  
E. Hirota ◽  
T. Iijima ◽  
K. Kuchitsu ◽  
D. A. Ramsay ◽  
...  


1958 ◽  
Vol 36 (9) ◽  
pp. 1223-1226 ◽  
Author(s):  
S. E. Sobering ◽  
C. A. Winkler

Cyanogen chloride and chlorine were the only gaseous products observed in the reaction of active nitrogen with carbon tetrachloride at 110° and 420 °C. The product yields tended towards limiting values at higher reactant flow rates, and increased with increase of temperature at all flow rates. The reactions of active nitrogen with chloroform and dichloromethane at 260° and 420 °C yielded hydrogen chloride, hydrogen cyanide, and cyanogen, in addition to cyanogen chloride and chlorine. The behavior of the product yields with reactant flow rates and temperature was similar to that of the products from carbon tetrachloride.



AIHA Journal ◽  
2002 ◽  
Vol 63 (4) ◽  
pp. 493-496 ◽  
Author(s):  
Timothy A. Kluchinsky ◽  
Paul B. Savage ◽  
Robert Fitz ◽  
Philip A. Smith






1997 ◽  
Vol 161 ◽  
pp. 179-187
Author(s):  
Clifford N. Matthews ◽  
Rose A. Pesce-Rodriguez ◽  
Shirley A. Liebman

AbstractHydrogen cyanide polymers – heterogeneous solids ranging in color from yellow to orange to brown to black – may be among the organic macromolecules most readily formed within the Solar System. The non-volatile black crust of comet Halley, for example, as well as the extensive orangebrown streaks in the atmosphere of Jupiter, might consist largely of such polymers synthesized from HCN formed by photolysis of methane and ammonia, the color observed depending on the concentration of HCN involved. Laboratory studies of these ubiquitous compounds point to the presence of polyamidine structures synthesized directly from hydrogen cyanide. These would be converted by water to polypeptides which can be further hydrolyzed to α-amino acids. Black polymers and multimers with conjugated ladder structures derived from HCN could also be formed and might well be the source of the many nitrogen heterocycles, adenine included, observed after pyrolysis. The dark brown color arising from the impacts of comet P/Shoemaker-Levy 9 on Jupiter might therefore be mainly caused by the presence of HCN polymers, whether originally present, deposited by the impactor or synthesized directly from HCN. Spectroscopic detection of these predicted macromolecules and their hydrolytic and pyrolytic by-products would strengthen significantly the hypothesis that cyanide polymerization is a preferred pathway for prebiotic and extraterrestrial chemistry.



1996 ◽  
Vol 88 (3) ◽  
pp. 673-682 ◽  
Author(s):  
K. HINDS ◽  
A.C. LEGON ◽  
J.H. HOLLOWAY


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