Growth of Phases with Narrow Homogeneity Range and Line Compounds by Interdiffusion

Author(s):  
Aloke Paul ◽  
Tomi Laurila ◽  
Vesa Vuorinen ◽  
Sergiy V. Divinski
1992 ◽  
Vol 47 (10) ◽  
pp. 1351-1354 ◽  
Author(s):  
Viktor Keimes ◽  
Albrecht Mewis

The compounds Mg2Ni3P and Mg2Ni3As were prepared by heating the elements. Their structures have been determined from single-crystal X-ray data. The structure of the phosphide is a rhombohedral ternary variant of the cubic Laves structure type MgCu2 (R 3̄ m; hexagonal lattice constants: a = 4.971(0) Å, c = 10.961(2) Å). The ordered substitution of one quarter of the metal atoms by phosphorus and the resulting shorter distances are responsible for the rhombohedral symmetry.The arsenide crystallizes in the MgCu2 type structure (Fd 3 m; a = 6.891(1)A, composition Mg2Ni3As) with a statistic distribution of the Ni and As atoms; the relevant homogeneity range extends from Mg2Ni2.9As1.1 to Mg2Ni3.5As0.5.


1973 ◽  
Vol 18 (1) ◽  
pp. 63-69 ◽  
Author(s):  
V. P. Zhuze ◽  
E. V. Goncharova ◽  
N. F. Kartenko ◽  
T. I. Komarova ◽  
L. S. Parfeneva ◽  
...  

2005 ◽  
Vol 53 (13) ◽  
pp. 3679-3687 ◽  
Author(s):  
Carlos Angelo Nunes ◽  
Dariusz Kaczorowski ◽  
Peter Rogl ◽  
Márcia Regina Baldissera ◽  
Paulo Atsushi Suzuki ◽  
...  

2007 ◽  
Vol 414 (1) ◽  
pp. 110-111 ◽  
Author(s):  
V. F. Balakirev ◽  
O. M. Fedorova ◽  
S. Kh. Estemirova ◽  
Yu. V. Golikov
Keyword(s):  

1980 ◽  
Vol 34 (4) ◽  
pp. iii
Author(s):  
H. Rau
Keyword(s):  

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