Wet Chemical Approaches for Chemical Functionalization of Silicon and Titanium Nanomaterials

Author(s):  
Kerrilee A. Stewart ◽  
Harinder Pal Singh Missan
Langmuir ◽  
2012 ◽  
Vol 28 (10) ◽  
pp. 4672-4682 ◽  
Author(s):  
Sabrina L. Peczonczyk ◽  
Jhindan Mukherjee ◽  
Azhar I. Carim ◽  
Stephen Maldonado

2015 ◽  
Vol 39 (7) ◽  
pp. 5096-5099 ◽  
Author(s):  
Rongbing Yu ◽  
Shupeng Zhang ◽  
Yuting Luo ◽  
Ruofei Bai ◽  
Jiangfang Zhou ◽  
...  

The successful wet chemical functionalization of graphene oxide with polystyrene offered the possibility of nucleophilic substitution in heterogeneous phase reactions.


2015 ◽  
Vol 119 (3) ◽  
pp. 1338-1345 ◽  
Author(s):  
Elizabeth S. Brown ◽  
Sabrina L. Peczonczyk ◽  
Stephen Maldonado

2012 ◽  
Vol 46 (1) ◽  
pp. 87-96 ◽  
Author(s):  
Andreas Hirsch ◽  
Jan M. Englert ◽  
Frank Hauke

Author(s):  
Pratibha L. Gai ◽  
M. A. Saltzberg ◽  
L.G. Hanna ◽  
S.C. Winchester

Silica based ceramics are some of the most fundamental in crystal chemistry. The cristobalite form of silica has two modifications, α (low temperature, tetragonal form) and β (high temperature, cubic form). This paper describes our structural studies of unusual chemically stabilized cristobalite (CSC) material, a room temperature silica-based ceramic containing small amounts of dopants, prepared by a wet chemical route. It displays many of the structural charatcteristics of the high temperature β-cristobalite (∼270°C), but does not undergo phase inversion to α-cristobalite upon cooling. The Structure of α-cristobalite is well established, but that of β is not yet fully understood.Compositions with varying Ca/Al ratio and substitutions in cristobalite were prepared in the series, CaO:Al2O3:SiO2 : 3-x: x : 40, with x= 0-3. For CSC, a clear sol was prepared from Du Pont colloidal silica, Ludox AS-40®, aluminium nitrate nonahydrate, and calcium nitrate hexahydrate in proportions to form a final composition 1:2:40 composition.


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