Stereoelective Anionic Polymerization of Chiral Vinyl Monomers Via Interconverting Ion Pair Epimers

Author(s):  
Mark A. Buese ◽  
Thieo E. Hogen-Esch

1975 ◽  
Vol 7 (3) ◽  
pp. 372-381 ◽  
Author(s):  
Masao Tomoi ◽  
Teruo Onozawa ◽  
Kenji Seki ◽  
Hiroshi Kakiuchi


1994 ◽  
Vol 88 (1) ◽  
pp. 177-189 ◽  
Author(s):  
Thomas Zundel ◽  
Jian Ming Yu ◽  
Collège De France






2004 ◽  
Vol 7 (1-2) ◽  
pp. 135-150 ◽  
Author(s):  
Boris A. Rozenberg


1958 ◽  
Vol 35 (7) ◽  
pp. 345 ◽  
Author(s):  
Albert Zilkha ◽  
Michael Albeck ◽  
Max Frankel


1970 ◽  
Vol 48 (13) ◽  
pp. 2031-2034 ◽  
Author(s):  
G. Löhr ◽  
S. Bywater

The propagation reaction in the anionic polymerization of styrene in oxepane has been studied as a function of temperature and concentration of polystyrylsodium. Conductance measurements on polystyrylsodium were also made together with determinations of density, viscosity, dielectric constant, and dipole moment of oxepane itself. The measurements enabled the propagation rate constant to be determined of the polystyryl anion at 30 °C and of the ion-pair over a wide temperature range. The results have been compared with those obtained in tetrahydrofuran and tetrahydropyran.





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