Multiple Mössbauer Spectra Data Acquisition with an In-situ Cyclic Voltammetry System

2002 ◽  
pp. 21-24 ◽  
Author(s):  
T L Greaves ◽  
J D Cashion ◽  
A L Benci ◽  
N K Jaggi ◽  
C Hogan ◽  
...  
1999 ◽  
Vol 64 (12) ◽  
pp. 2044-2060 ◽  
Author(s):  
Karel Bouzek ◽  
Martin Nejezchleba

In situ Mössbauer spectra of the iron electrode at anodic potential were measured in sodium hydroxide solution over a wide range of concentrations (0.1 - 14 mol l-1). It was found that the in situ Mössbauer spectra exhibit generally one sextet and one doublet corresponding to the oxide layer on the anode surface. Parameters of these spectra show only minor variations within the electrolyte concentration range of 0.1 - 7 M NaOH. A pronounced change in the spectra was observed in 14 M NaOH. The major processes taking place in the anode surface layer are based on the break-down of protective properties of the passive layer, incipient intense metal dissolution and subsequent oxidation. Important differences were also found between in situ and ex situ spectra measurements.


1988 ◽  
Vol 42 (1-4) ◽  
pp. 1181-1184 ◽  
Author(s):  
Rong-jie Zhou ◽  
Fa-shen Li ◽  
Zhi-fan Zhang

1979 ◽  
Vol 40 (C2) ◽  
pp. C2-669-C2-670 ◽  
Author(s):  
E. De Grave ◽  
A. Govaert ◽  
D. Chambaere ◽  
G. Robbrecht

2001 ◽  
Author(s):  
Olga Kocharovskaya ◽  
Zameer Hasan ◽  
James Carroll

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