Linking cave sediments and soil magnetism in the Urșilor cave (Romania)

<p>Cyclical changes in the magnetic mineral assemblages have been observed in numerous sedimentary records confirming the relationship between rock magnetism and past global change. Several studies have shown that the magnetic susceptibility data of cave sediments reflect both long- and short-term climatic oscillations. These magnetic susceptibility variations are attributed to changes in climate-controlled pedogenesis which influence the production of low coercivity magnetic mineral phases, magnetite, and maghemite outside the cave. These soils with climate-dependent magnetic properties are then washed, blown, or tracked into the cave where they accumulate, creating the changes observed in rock magnetic data. We present a rockmagnetism study of the sediments from the Urșilor cave and the soils above the cave. Our focus is the detailed characterization of the ferromagnetic mineralogy preserved in the cave sediments and its links with potential soil sources. In the cave, we sampled four sections (2-3 m high) consisting mainly of silts and clays, with some sand layers. The age of the sediments is older than 40 ka. At the surface, we sampled various types of soils from 9 sites. For all samples, we measured: variation of magnetic susceptibility with frequency (976 and 15616 Hz), the anisotropy of magnetic susceptibility, isothermal remanent magnetization, and anhysteretic remanent magnetization. Because soils are characterized by the presence of superparamagnetic magnetite produced by pedogenesis which can be detected by the frequency dependence of magnetic susceptibility, we also measured the frequency dependence of soils and selected cave sediment samples at 13 frequencies (between 128 and 512000 Hz). Multi-frequencies measurements of the magnetic susceptibility of recent soils show that all the sampled soils have a strong frequency dependence indicating the presence of superparamagnetic particles produced by pedogenesis. Most of the sediment samples have an important frequency dependence similar to the one observed in the recent soils. As a preliminary conclusion, we can state that most of the fine cave sediments contain superparamagnetic particles, which can be probably attributed to soils transported into the cave by erosion. These results suggest that during the deposition of high magnetic susceptibility sediments it was a climate favorable for intense pedogenesis. The interpretation of the intervals with lower values of magnetic susceptibility is still under investigation to decide if represents a climatic signal or a change in the dynamics of sediment transport. <strong>Acknowledgment:</strong> The research leading to these results has received funding from the EEA Grants 2014-2021, under Project contract no. EEA-RO-NO-2018-0126.</p>

Superparamagnetic nanoparticles with LC polymer brush shell as efficient dopants for ferronematic phases

A promising route for the fabrication of ferronematic phases is the attachment of a LC polymer shell onto the surface of nanoparticles. Here, we extend this approach to ferronematic phases based on superparamagnetic particles in a 5CB matrix.

The Performance of the Magneto-Impedance Effect for the Detection of Superparamagnetic Particles

The performance of magneto-impedance sensors to detect the presence and concentration of magnetic nanoparticles is investigated, using finite element calculations to directly solve Maxwell’s equations. In the case of superparamagnetic particles that are not sufficiently magnetized by an external field, it is assumed that the sensitivity of the magneto-impedance sensor to the presence of magnetic nanoparticles comes from the influence of their magnetic permeability on the sensor impedance, and not from the stray magnetic field that the particles produce. The results obtained not only justify this hypothesis, but also provide an explanation for the discrepancies found in the literature about the response of magneto-impedance sensors to the presence of magnetic nanoparticles, where some authors report an increasing magneto-impedance signal when the concentration of magnetic nanoparticles is increased, while others report a decreasing tendency. Additionally, it is demonstrated that sensors with lower magneto-impedance response display larger sensitivities to the presence of magnetic nanoparticles, indicating that the use of plain, nonmagnetic conductors as sensing materials can be beneficial, at least in the case of superparamagnetic particles insufficiently magnetized in an external magnetic field.