Kinetics of osmium(VIII) catalysis of periodate oxidation of DMF in aqueous alkaline medium

1994 ◽  
Vol 19 (2) ◽  
pp. 215-217 ◽  
Author(s):  
Gangadhar H. Hugar ◽  
Sharanappa T. Nandibewoor
Keyword(s):  
Alkaline Medium ◽  
Periodate Oxidation ◽  
Aqueous Alkaline Medium ◽  
Kinetics Of

scholarly journals Kinetics of periodate oxidation of polyoxyethylene – 300, a biodegradable pharmaceutical polymer

2019 ◽  
Vol 10 (4) ◽  
pp. 2830-2836
Author(s):  
Koteswara Rao K.V.S ◽  
Venkata Nadh R ◽  
Venkata Ratnam K
Keyword(s):  
Temperature Dependence ◽  
Alkaline Medium ◽  
Reaction Rate ◽  
Periodate Oxidation ◽  
Activation Parameters ◽  
Aqueous Alkaline Medium ◽  
Title Reaction ◽  
First Order ◽  
The Stability ◽  
Kinetics Of

Polyoxyethylene Oxide – 300 (POE) is a well-known biodegradable pharmaceutical polymer. In order to understand the stability of POE and to derive the reaction rate law, the title reaction was carried out in aqueous alkaline medium, Reaction was found to be first order dependent on the concentration oxidant (periodate) and independent of substrate (POE) concentration. A retardation of reaction rate with an increase in hydroxide concentration shows an inverse fractional order in it. Based on the studies of the temperature dependence of reaction, evaluated the activation parameters.

Mechanism of Ruthenium (III) Catalysis of Periodate Oxidation of Aldoses in Aqueous Alkaline Medium

2004 ◽  
Vol 95 (3/4) ◽  
pp. 135-141 ◽  
Author(s):  
Ashok Kumar Singh ◽  
N. Chaurasia ◽  
Shahla Rahmani ◽  
Jaya Srivastava ◽  
Bharat Singh
Keyword(s):  
Alkaline Medium ◽  
Periodate Oxidation ◽  
Aqueous Alkaline Medium

Oxidation of (+)-(R)-Pantothenic Acid by Aqueous Alkaline Potassium Permanganate: A Kinetic and Mechanistic Approach

2002 ◽  
Vol 216 (6) ◽  
Author(s):  
S.M. Desai ◽  
N.N. Halligudi ◽  
S.K. Mavalangi ◽  
S.T. Nandibewoor
Keyword(s):  
Ionic Strength ◽  
Potassium Permanganate ◽  
Alkaline Medium ◽  
Pantothenic Acid ◽  
Constant Ionic Strength ◽  
Aqueous Alkaline Medium ◽  
Kinetics Of Oxidation ◽  
Mechanistic Approach ◽  
Kinetics Of

The kinetics of oxidation of (+)-(R)-pantothenic acid (PA) by permanganate in aqueous alkaline medium at constant ionic strength 0.20 mol dm

scholarly journals Kinetics of Electron Transfer from Cyclic Ketones to Ni(IV) Periodate Complex in Aqueous Alkaline Medium

1989 ◽  
Vol 62 (4) ◽  
pp. 1300-1303 ◽  
Author(s):  
Jaffar Ali Khan ◽  
U. Chandraiah ◽  
B. Kishore Kumar ◽  
Sushama Kandlikar
Keyword(s):  
Electron Transfer ◽  
Alkaline Medium ◽  
Aqueous Alkaline Medium ◽  
Cyclic Ketones ◽  
Kinetics Of
Sign in / Sign up

Export Citation Format

Share Document