Determination of diquat in biological materials by electron spin resonance spectroscopy

1990 ◽  
Vol 103 (8) ◽  
Author(s):  
Kayoko Minakata ◽  
Osamu Suzuki ◽  
Takeshi Kumazawa ◽  
Minoru Asano ◽  
Naoko Harada
1990 ◽  
Vol 103 (8) ◽  
pp. 599-607 ◽  
Author(s):  
Kayoko Minakata ◽  
Osamu Suzuki ◽  
Takeshi Kumazawa ◽  
Minoru Asano ◽  
Naoko Harada

Science ◽  
1983 ◽  
Vol 222 (4629) ◽  
pp. 1235-1236 ◽  
Author(s):  
G. C. HILLMAN ◽  
G. V. ROBINS ◽  
D. ODUWOLE ◽  
K. D. SALES ◽  
D. A. C. MCNEIL

1987 ◽  
Vol 40 (1) ◽  
pp. 157 ◽  
Author(s):  
ALJ Beckwith ◽  
SA Glover

The hex-5-enyl (1), 3-oxahex-5-enyl (6), 2-oxahex-5-enyl (9) and 2,2-dimethylbut-3- enoyloxymethyl (13) radicals have been generated by interaction of the corresponding bromides with trialkyltin or trialkylgermanium radicals, and their rate constants and activation parameters for cyclization have been determined by kinetic e.s.r . spectroscopy. The 3-oxa species (6) undergo 1,5-ring closure more rapidly than does hex-5-enyl radical (1) because of favourable stereoelectronic factors. Spectral evidence has been obtained for restricted rotation about the O-CH2* bond in the 2-oxa radical (9) as a consequence of which its ring closure is relatively slow. Similarly, 1,5-ring closure of the ester derived radical (13) is slow because of unfavourable conformational effects arising from restricted rotation about the CO-O bond. The radical (22) formed from allyl bromoacetate does not undergo ring closure. Spectral data have been obtained for various radicals (16), (19), (23), (24) formed by intermolecular addition.


2018 ◽  
Vol 141 ◽  
pp. 444-450 ◽  
Author(s):  
Sizhu Tian ◽  
Jia Jiang ◽  
Shuang Zang ◽  
Kun Wang ◽  
Yong Yu ◽  
...  

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