Description of equilibrium bond lengths with the use of spectroscopic parametrization of the CNDO method including transition metals

1992 ◽  
Vol 32 (4) ◽  
pp. 471-476
Author(s):  
V. N. Yakovlev ◽  
N. S. Panina ◽  
V. �. L'vovskii
Keyword(s):  
Transition Metals ◽  
Cndo Method ◽  
Bond Lengths ◽  
Spectroscopic Parametrization

Variant of the ?Spectroscopic? parametrization of the CNDO method including transition metals

1987 ◽  
Vol 27 (4) ◽  
pp. 656-657 ◽  
Author(s):  
V. N. Yakovlev ◽  
V. E. L'vovskii ◽  
N. S. Panina
Keyword(s):  
Transition Metals ◽  
Cndo Method ◽  
Spectroscopic Parametrization

Distortion isomers of PtM, Pt2M, PtM2 and PtMM′ (M = non-transition metals) derivatives-structural aspects

2018 ◽  
Vol 0 (0) ◽  
Author(s):  
Milan Melník ◽  
Peter Mikuš
Keyword(s):  
Transition Metals ◽  
Structural Parameters ◽  
Bond Angles ◽  
Bond Lengths ◽  
Metal Atoms ◽  
Independent Molecules ◽  
Structural Aspects

Abstract An analysis of the structural parameters of PtM, Pt2M, PtM2 and PtMM′ (M = non-transition metals) derivatives shows that each complex contains two crystallographically independent molecules within the same crystal. The respective molecules differ by the degrees of distortion and exemplify the distortion isomerism. These are discussed in terms of the coordination with the platinum and the M atoms and the correlations are drawn among the metal atoms, donor atoms, bond lengths and bond angles. A wide variety of non-transition metals (Sn, Ga, In, Tl, Zn, Cd, Hg, Sb) exist, among which the most prevalent is Sn.

scholarly journals Metal-metal bond lengths in complexes of transition metals

1976 ◽  
Vol 73 (12) ◽  
pp. 4290-4293 ◽  
Author(s):  
L. Pauling
Keyword(s):  
Transition Metals ◽  
Bond Lengths ◽  
Metal Bond ◽  
Metal Metal ◽  
Complexes Of Transition Metals

A survey of terminal chalcogenido complexes of the transition metals: trends in their distribution and the variation of their ME bond lengths

Polyhedron ◽  
1997 ◽  
Vol 16 (7) ◽  
pp. 1031-1045 ◽  
Author(s):  
Tina M. Trnka ◽  
Gerard Parkin
Keyword(s):  
Transition Metals ◽  
Bond Lengths

Use of the CNDO method for the study of the electronic structure and properties of complexes of the transition metals

1977 ◽  
Vol 17 (3) ◽  
pp. 478-506 ◽  
Author(s):  
V. I. Baranovskii ◽  
O. V. Sizova ◽  
N. V. Ivanova
Keyword(s):  
Electronic Structure ◽  
Transition Metals ◽  
Structure And Properties ◽  
Cndo Method

MO study of Td-D4h equilibrium in complexes of transition metals. II. Equilibrium in tetrafluoro and tetrabromo complexes of atoms of the first transition row

1984 ◽  
Vol 49 (12) ◽  
pp. 2837-2856 ◽  
Author(s):  
Peter Pelikán ◽  
Marek Liška
Keyword(s):  
Electronic Structure ◽  
Transition Metals ◽  
Central Atom ◽  
Spin States ◽  
Cndo Method ◽  
Oxidation Degree ◽  
High Spin States ◽  
Square Planar ◽  
Complexes Of Transition Metals ◽  
Square Planar Complexes

The CNDO method for transition metals in the UHF version has been used to study the equilibrium of configuration isomers of tetrahedral and square-planar tetrafluoro and tetrabromo complexes of the first transition row atoms in the oxidation degree II (Mn(II), Fe(II), Co(II), Ni(II), Cu(II) both in low-spin and in high-spin states. The results show that the ability (given by electronic structure of the central atom) to form the square-planar complexes decreases monotonously in the series: Mn(II) > Fe(II) > Co(II) > Ni(II) > Cu(II). With respect to the effect of the electronic structure of ligands, the same ability decreases in the series: F- > Cl- > Br-.

Calculation of Equilibrium Bond Lengths by the CNDO Method

1967 ◽  
Vol 47 (5) ◽  
pp. 1876-1877 ◽  
Author(s):  
Gerald A. Segal
Keyword(s):  
Cndo Method ◽  
Bond Lengths
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