Determination of the metallic iron content of iron powders by the magnetometric method

1970 ◽  
Vol 9 (8) ◽  
pp. 619-624
Author(s):  
B. N. Putimtsev ◽  
A. A. Fedorov
Author(s):  
Zhiyong Xu ◽  
Jim Hwang ◽  
Robert Greenlund ◽  
Xiaodi Huang ◽  
Jinjing Luo ◽  
...  

2016 ◽  
Vol 52 (2) ◽  
pp. 151-155
Author(s):  
M.H. Morcali

The growing use of metallic iron in metallurgy and industrial chemical applications requires a fast, easy and cheap method for the determination of metallic iron, not merely in recyclable materials, such as iron pellets, reduced iron mill scale dust, electric arc furnace dust and pig iron, but from hot briquette iron (HBI) as well. This study investigates a new method for determination of metallic iron within HBI used for steel-making materials. The effects of reaction time, temperature, and stirring rate were studied. The concentration of iron was determined via Atomic Absorption Spectroscopy (AAS). After the optimization study, high-purity metallic iron powder (Sigma-Aldrich, PubChem Substance ID 24855469) was used to compare efficiencies and identify the optimum conditions; The present study was matched with international standard methods (BS ISO 5416:2006, IS 15774:2007). Results were consistent with certified values and metallic iron content could be determined within the 95% confidence level. The purposed method is easy, straightforward, and cheap.


1961 ◽  
Vol 38 (4) ◽  
pp. 545-562 ◽  
Author(s):  
L. Kecskés ◽  
F. Mutschler ◽  
I. Glós ◽  
E. Thán ◽  
I. Farkas ◽  
...  

ABSTRACT 1. An indirect paperchromatographic method is described for separating urinary oestrogens; this consists of the following steps: acidic hydrolysis, extraction with ether, dissociation of phenol-fractions with partition between the solvents. Previous purification of phenol fraction with the aid of paperchromatography. The elution of oestrogen containing fractions is followed by acetylation. Oestrogen acetate is isolated by re-chromatography. The chromatogram was developed after hydrolysis of the oestrogens 'in situ' on the paper. The quantity of oestrogens was determined indirectly, by means of an iron-reaction, after the elution of the iron content of the oestrogen spot, which was developed by the Jellinek-reaction. 2. The method described above is satisfactory for determining urinary oestrogen, 17β-oestradiol and oestriol, but could include 16-epioestriol and other oestrogenic metabolites. 3. The sensitivity of the method is 1.3–1.6 μg/24 hours. 4. The quantitative and qualitative determination of urinary oestrogens with the above mentioned method was performed in 50 pregnant and 9 non pregnant women, and also in 2 patients with granulosa cell tumour.


Sign in / Sign up

Export Citation Format

Share Document