There is a strong interest in what separates top-level performers from those who have yet to achieve the same level, across all performance domains. Advances in psychophysiology give insight into where these differences may lie in the minds and bodies of athletes. The present study compared gymnasts who were selected for the competitive lineup to those who were considered part of the Division I gymnastics beam squad but did not compete. This study compared their initial baselines, their response to heart rate variability and neurofeedback training, and their posttraining levels. Baseline differences existed for self-perception of consistency and confidence. There were no pre or post differences in heart rate variability measures. Sensorimotor rhythm electroencephalography (EEG) biofeedback training was associated with a decline in busy brain waves for the competitors. The competitors also had a lower ratio of intensity (intensity/high alpha) in both the pre- and post-EEG measures.