Determination of standard gibbs energies of formation of MgO, SrO, and BaO

1993 ◽  
Vol 24 (3) ◽  
pp. 487-492 ◽  
Author(s):  
Hideki Ono ◽  
Masaya Nakahata ◽  
Fumitaka Tsukihashi ◽  
Nobuo Sano
Keyword(s):  
Gibbs Energies

Determination of standard gibbs energies of formation of Cr2N and CrN

2001 ◽  
Vol 32 (6) ◽  
pp. 1113-1118 ◽  
Author(s):  
Hideki Ono-Nakazato ◽  
Kenji Taguchi ◽  
Tateo Usui ◽  
Keishi Tamura ◽  
Yuuji Tomatsu
Keyword(s):  
Gibbs Energies

Determination of Basicities of Organic Solvents and Absolute Electrode Potentials (E0-Values) of Monovalent Ions in Organic Solvents based on Absolute Values of Gibbs Energies of Solvation of Single Ions

2004 ◽  
Vol 218 (5) ◽  
pp. 515-550 ◽  
Author(s):  
Ranjana Bhattacharyya ◽  
S. C. Lahiri
Keyword(s):  
Organic Solvents ◽  
Gibbs Energies ◽  
Electrode Potentials ◽  
Induced Dipole ◽  
Single Scale ◽  
Monovalent Ions ◽  
Born Equation ◽  
The Absolute ◽  
Single Standard

AbstractSingle ion Gibbs energies of monovalent ions in fourteen solvents (water, methanol, NMF, PC, ethanol, n-propanol, iso-propanol, n-butanol, t-butanol, ethylene glycol, acetone, THF, 1,4-dioxan, acetonitrile) with or without (ion–dipole, ion–induced dipole, ion–quadrupole) interactions were determined. The basicity of the solvents was determined from the absolute values of ΔG0solvation(H+) or ΔG0solution(H+) based on single standard state utilising the modified Born equation suggested by Lahiri. The method involves no arbitrary assumptions. A single scale for the absolute electrode potentials (E0 values) has been determined based on calculated Gibbs energies of solvation or solution of single ions. Appropriation of Gibbs energies of solvation of electrolytes into single ion values is not possible. Gibbs energies of formation of electrolytes in solvents must be taken into consideration. Stabilisation energies of electrolytes (MX) in solvents akin to lattice energies in solids were determined.

The Ideal Ionic Liquid Salt Bridge for Direct Determination of Gibbs Energies of Transfer of Single Ions, Part II: Evaluation of the Role of Ion Solvation and Ion Mobilities

2018 ◽  
Vol 130 (9) ◽  
pp. 2372-2376 ◽  
Author(s):  
Andreas Ermantraut ◽  
Valentin Radtke ◽  
Niklas Gebel ◽  
Daniel Himmel ◽  
Thorsten Koslowski ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Direct Determination ◽  
Salt Bridge ◽  
Ion Solvation ◽  
Gibbs Energies ◽  
Liquid Salt ◽  
Gibbs Energies Of Transfer ◽  
The Ideal

Calcium Ruthenates: Determination of Gibbs Energies of Formation Using Electrochemical Cells.

ChemInform ◽  
2003 ◽  
Vol 34 (27) ◽  
Author(s):  
K. Thomas Jacob ◽  
Kay Thi Lwin ◽  
Yoshio Waseda
Keyword(s):  
Electrochemical Cells ◽  
Gibbs Energies
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